Search for dissertations about: "Makromolekylär kemi"

Showing result 1 - 5 of 11 swedish dissertations containing the words Makromolekylär kemi.

  2. 1. TRÖGER´S BASE AS SCAFFOLD FOR SYNTHETIC RECEPTORS

    Author : Carlos Solano; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; Organisk kemi; Organic chemistry; Makromolekylär kemi; Macromolecular chemistry; Molecular Recognition; Tröger´s base; Synthetic Receptors; Fysikalisk kemi;

    Abstract : This work focuses on the use of the Tröger´s base as organic scaffold for the construction of synthetic receptors for different classes of organic molecules. The structural properties of the Tröger's base, i.e. chirality, rigidity and curvature, allow for synthetic modifications towards the recognition of different molecules. READ MORE

  4. 2. Water diffusion and free volume in hydrophilic polymers

    Author : Charlotte Trotzig; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; free volume; self-diffusion; degree of crystallinity; glass transition temperature; tensile storage modulus; surface tension; isotherm; HPMC; PEO; water; triacetin; clay; Macromolecular chemistry; dynamic mechanical analysis; Fysikalisk kemi; differential scanning calorimetry; nuclear magnetic resonance; positron annihilation; Makromolekylär kemi;

    Abstract : During moisture uptake in polymers, the diffusion of the water molecules is believed to occur via unoccupied voids. These voids are called free volume cavities and their sizes are continuously altered when the moisture content in the polymer is enhanced. READ MORE

  5. 3. Flexible Synthesis of Rigid Cyclophanes - Synthesis and derivatisation of 2,7-diaza-1,2,3,6,7,8-hexahydropyrene into chiral macrocycles

    Author : Jörgen Toftered; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Macromolecular chemistry; Makromolekylär kemi; biomimetic; cross-linking; thiourea; urea; difluorodinitrobenzene; cyclodimerisation; Cyclophanes; macrocycles;

    Abstract : Rigid, chiral and amphiphilic cyclophanes of potential use as biomimetic host molecules were prepared by cyclic dimerisation of chiral diamino building blocks with amino-reactive cross-linking reagents. A reliable synthesis of the scaffold 2,7-diaza-1,2,3,6,7,8-hexahydropyrene was developed. READ MORE

  6. 4. Proton-Conducting Sulfonated and Phosphonated Polymers and Fuel Cell Membranes by Chemical Modification of Polysulfones

    Author : Benoit Lafitte; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Macromolecular chemistry; Makromolekylär kemi; Material technology; Materiallära; materialteknik; chemical modification; lithiation; fuel cells; polyelectrolyte; sulfonated polymers; proton-conducting polymer membranes polysulfone; phosphonated polymers;

    Abstract : The proton exchange membrane fuel cell (PEMFC) is currently emerging as an efficient and environmentally friendly power source. The technology is very complex and relies ultimately on materials and components which need further development. READ MORE

  7. 5. Intrinsically Proton-Conducting Benzimidazole Units Tethered to Different Polymer Chain Architectures

    Author : Christian Persson; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Polymerteknik; biopolymers; Kemiteknik och kemisk teknologi; Polymer technology; Chemical technology and engineering; Materiallära; materialteknik; Material technology; Makromolekylär kemi; Macromolecular chemistry; proton-exchange membrane fuel cell; structure diffusion; thiol-ene reaction; segmental mobility; high temperature; benzimidazole; block copolymers; polymer electrolyte; anhydrous proton conductivity;

    Abstract : Proton transport is a fundamental process that can be found in many systems in nature, as well as in technical devices, such as fuel cells, electrochromic devices and various types of sensors. Fuel cell technology is considered as environmentally friendly because fuel cells are not limited by the Carnot cycle, and efficiently converts chemical energy into electrical energy which can be used for powering cars, laptops, buildings etc. READ MORE