Search for dissertations about: "Mechanism reduction"

Showing result 1 - 5 of 617 swedish dissertations containing the words Mechanism reduction.

  2. 1. Structure-Reactivity Correlations for Reactions of Palladium(II) and Platinum(IV) Complexes

    Author : Tiesheng Shi; Kemiska institutionen; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; thiol; l-methionine; maleic acid; carboxylic acid; thioether; platinum IV ; palladium II ; linear free energy relationship; volumes of activation; structure-reactivity correlation; reduction; substitution; equilibria; kinetics; mechanism; glutathione; Animal physiology; Djurfysiologi;

    Abstract : The kinetics and mechanism for substitution reactions on tetraaquapalladium(II) by an extended series of thioethers, a great number of carboxylic acids, and olefins have been studied by use of UV-VIS, stopped-flow, and high-pressure stopped-flow spectrophotometry and NMR spectroscopy. Second-order rate constants k and activation parameters (activation enthalpies, entropies, and volumes) for formation of monodentate 1:1 complexes have been determined. READ MORE

  4. 2. Fundamental Studies Related to Gaseous Reduction of Iron Oxide

    Author : Mania Kazemi; Du Sichen; Ioannis Arvanitidis; KTH; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Direct reduction; iron ore; cementite; reduction model;

    Abstract : The demands for increasing the efficiency and lowering the environmental effects in iron and steelmaking industries have given rise to interests in application of direct reduction (DR) processes for production of iron by different gases. These advancements require comprehensive models for better control of the process conditions and the product properties. READ MORE

  5. 3. Automatic Reduction Procedures for Chemical Mechanisms in Reactive Systems

    Author : Terese Lövås; Förbränningsfysik; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Mechanism Reduction; Combustion; Physics; Emissions; Fysik; Fysicumarkivet A:2002:Lövås;

    Abstract : To deal with complex physical and chemical processes in reactive systems, such as combustion processes, it is necessary to find methods that simplify modelling in such a way that it becomes both more comprehensible and practically useful. In the work reported here a method for automatically reducing chemical reaction mechanisms has been developed for use in computer simulations of various combustion systems. READ MORE

  6. 4. Homogeneous Ignition - Chemical Kinetic Studies for IC-Engine Applications

    Author : Per Amnéus; Förbränningsfysik; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Skeletal mechanism; Mechanism reduction; n-heptane; iso-octane; formaldehyde; methane; Motors and propulsion systems; Motorer; framdrivningssystem; Physics; Fysik; Detailed chemistry; Kinetic calculations; Engine knock; Homogeneous charge compression ignition; HCCI; Fysicumarkivet A:2002:Amnéus;

    Abstract : Calculations on a Homogeneous Charge Compression Ignition (HCCI) engine have been performed. Zero-dimensional models were used. The simplest model compressed the gas to auto-ignition, using temperature and pressure at a certain crank angle position obtained from engine experiments. READ MORE

  7. 5. BlueBellMouse. A Tool for Kinetic Model Development

    Author : Raffaella Bellanca; Förbränningsfysik; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; combustion; HCCI; reduction; engine; kinetic; simulation; graphical user interface; GUI; optimization; chemical mechanism; Physics; Fysik; Fysicumarkivet A:2004:Bellanca;

    Abstract : The simulation of physical phenomena occurring in chemical reactors requires the description of the kinetics involved in the underlying combustion process. Kinetic models are developed for this purpose. READ MORE