Search for dissertations about: "SUBSTITUTION"

Showing result 1 - 5 of 735 swedish dissertations containing the word SUBSTITUTION.

  2. 1. Experimental Vitreous Substitution

    Author : Henrik Barth; Lund Oftalmologi; []
    Keywords : MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Retinal Detachment; Vitreous Body : surgery; Retina cytology metabolism surgery; Retina: Function; Retina: Inflammation; Retinal Detachment; Vitreous Body : surgery; Vitreous substitute; Vitrectomy;

    Abstract : Blindness and visual disability are common following vitreoretinal pathologies such as open globe injury, proliferative diabetic retinopathy, and rhegmatogenous retinal detachment (RRD). These conditions often necessitate surgical intervention using vitrectomy with a tamponading vitreous substitute. READ MORE

  4. 2. Palladium-Catalyzed Nucleophilic Substitution of Alcohols : Mechanistic Studies and Synthetic Applications

    Author : Supaporn Sawadjoon; Joseph Samec; Takao Ikariya; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; palladium; nucleophilic substitution; mechanism; Organic Chemistry; Organisk kemi;

    Abstract : This thesis deals with the palladium-catalyzed nucleophilic substitution of π-activated alcohols in which the C–O bond of a non-manipulated hydroxyl group is cleaved. The thesis is divided in two chapters describing two different catalytic systems. READ MORE

  5. 3. Platinum(II) and Palladium (II) Complexes with Group 14 and 15 Donor Ligands. Synthesis, Structure and Substitution Mechanisms

    Author : Ola Wendt; Kemiska institutionen; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; mechanism; kinetics; substitution; platinum; palladium; aryl; silyl; nitrile; triphenylstibine; NMR; IR; Raman; X-ray crystallography; stopped-flow; synthesis; Inorganic chemistry; Oorganisk kemi;

    Abstract : The present thesis deals with Pd(II) and Pt(II) complexes with group 14 and 15 donor ligands. Such complexes have been prepared and investigated mainly with regard to their ground state structures and the mechanism according to which they undergo substitution. READ MORE

  6. 4. Ligand Substitution and Solvent : Exchange Reactions of Palladium(II) and Platinum(II) Acetonitrile and Dimethyl Sulfoxide Complexes. A High-Pressure Stopped-Flow and NMR Study

    Author : Björn Hellquist; Jönköping University; []
    Keywords : ;

    Abstract : .... READ MORE

  7. 5. Concerted or Stepwise? : β-Elimination, Nucleophilic Substitution, Copper Catalysed Aziridination and Ruthenium Catalysed Transfer Hydrogenation Studied by Kinetic Isotope Effects and Linear Free-Energy Relationships

    Author : Per Ryberg; Heinz F. Koch; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Kinetic isotope effect; linear free energy relationship; elimination; substitution; aziridination; transfer hydrogenation; Organisk kemi; Organic chemistry; Organisk kemi; organisk kemi; Organic Chemistry;

    Abstract : This thesis describes the use of kinetic isotope effects, linear free energy relationships and stereochamical studies to distinguish between different mechanistic alternatives and to obtain information about transition state structure.In the first part fluorine and deuterium kinetic isotope effects were determined for the base promoted HF elimination from 4-fluoro-4-(4’-nitrophenyl)butane-2-on. READ MORE