Search for dissertations about: "Silenes"

Found 3 swedish dissertations containing the word Silenes.

  2. 1. Lowcoordinated Silicon and Hypercoordinated Carbon : Structure and Stability of Silicon Analogs of Alkenes and Carbon Analogs of Silicates

    Author : Anders M. Eklöf; Henrik Ottosson; Sten Lunell; Thomas Müller; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; silenes; zwitterionic silenes; silenolates; reverse polarization; natural resonance theory; hypervalent carbon; hypercoordinated carbon; thermolysis; lowcoordinated silicon; Organic chemistry; Organisk kemi;

    Abstract : Quantum chemical studies on lowcoordinated group 14-16 compounds have been performed. This thesis focuses particularly on silenes influenced by reverse Siδ-=Cδ+ bond polarization. Hypercoordinated carbon compounds are also studied. READ MORE

  4. 2. Organic Heavy Group 14 Element Compounds : A Study of Their Chemical Bonding Properties Directed Towards Applications as Molecular Wires and in Synthesis

    Author : Julius Tibbelin; Henrik Ottosson; Christoph Marschner; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Silicon; Group 14 Elements; Silenes; Conjugation; Chemical Bonding; Electronic Structure; Protecting Group Chemistry; Physical organic chemistry; Fysikalisk organisk kemi; Chemistry with specialization in Organic Chemistry; Kemi med inriktning mot organisk kemi;

    Abstract : The research described herein includes synthesis, spectroscopy, and quantum chemical calculations with focus on the characteristic properties of compounds with bonds between carbon and the heavier Group 14 elements.The chapters based on the first four papers concern σ- and σ/π-conjugated compounds, although the focus of the first paper is on ring strain of bicyclo[1. READ MORE

  5. 3. Synthesis and Reactivity Studies of Zwitterionic Silenes and 2-Silenolates

    Author : Tamaz Guliashvili; Henrik Ottosson; Kim M. Baines; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Silicon; Zwitterionic Silene; 2-Silenolate; Diels-Alder Reaction; Silacyclohexene; X-ray Crystallography; Organisk kemi; Organic chemistry; Organisk kemi;

    Abstract : This thesis describes synthesis and reactivity studies of 2-amino-2-siloxysilenes and 2-silenolates, species that are strongly influenced by reversed Si=C bond polarization, i.e. an Siδ-=Cδ+ polarization as compared to the natural Siδ+=Cδ- polarization. READ MORE