Search for dissertations about: "boronate"

Showing result 1 - 5 of 11 swedish dissertations containing the word boronate.

  2. 1. New Arylation Strategies Based on Organomain Group Reactivity

    Author : Carina Sollert; Lukasz T. Pilarski; Brenton L. DeBoef; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; C-H functionalisation; catalysis; ruthenium; indole; silylation; boronate; boryl aryne; aryne distortion; Chemistry with specialization in Organic Chemistry; Kemi med inriktning mot organisk kemi;

    Abstract : The work in this thesis describes the development of new heteroarylation methodology based on transition metal-catalysed C-H functionalisation and the properties of organomain group compounds. The underlying reaction mechanisms and reactivity patterns of the (hetero)arene substrates are also investigated. READ MORE

  4. 2. Responsive Molecular Systems through Dynamic Covalent Chemistry

    Author : Antanas Karalius; Zoltan Szabo; Stefan Matile; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; stimuli-responsiveness; dynamic covalent reactions; systems chemistry; constitutional dynamics; non-equilibrium systems; nitroaldol reaction; dynamers; reversible polymerization; boronate ester; imine ligand; metal coordination; self–assembly; emergent properties; network topology.; stimuli-responsivitet; dynamiska kovalenta reaktioner; systemkemi; konstitutionell dynamik; icke-jämviktssystem; nitroaldolreaktion; dynamerer; reversibel polymerisation; boronester; iminligand; metallkoordination; själv-organisation; emergenta egenskaper; nätverkstopologi.; Kemi; Chemistry;

    Abstract : Nature tends to inspire research in chemistry. Systems that emerge from molecules interacting via reaction networks is something that life has mastered over the course of evolution in order to produce complexity. Dynamic reactions are key in systems chemistry, where reaction networks give rise to complex, emergent behavior. READ MORE

  5. 3. Transition metal-catalyzed allylic and vinylic functionalization : Method development and mechanistic investigations

    Author : Johanna M. Larsson; Kálmán J. Szabó; Dennis G. Hall; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; palladium; copper; catalysis; Heck reaction; C-H functionalization; allylic substitution; silylation; borylation; trifluoromethylation; fluorination; mechanistic study; transition metal; alkene; allylic silane; allylic boronate; allylic fluoride; organisk kemi; Organic Chemistry;

    Abstract : The use of small molecule building blocks in, for example, pharmaceutical research and new material development, creates a need for new and improved organic synthesis methods. The use of transition metals as mediators and catalysts opens up new reaction pathways that have made the synthesis of completely new compounds possible as well as greatly improved the synthetic routes to known compounds. READ MORE

  6. 4. Carbohydrate-specific, boronate-containing copolymers: from sugar-sensing to cell adhesion

    Author : Marina Kuzimenkova; Bioteknik; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; surface grafting; chemisorption; boronic acid; carbohydrates; affinity; chromatography; smart polymers; biomimetics; hydrogels; molecular recognition; diffusion; sugar-sensing; cell adhesion;

    Abstract : Carbohydrates play a major role in many cell recognition events and metabolic pathways of living organisms. Synthetic carbohydrate receptors are of great interest for the chemical design of sugar sensors, materials for cell separation, cell immobilization, drug delivery and other biomedical/biotechnological applications. READ MORE

  7. 5. Control of Aryne Capture Regioselectivity via Fluoroboronate-induced Distortion

    Author : Matic Hribersek; Lukasz Pilarski; Carl Johan Wallentin; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES;

    Abstract : Arynes are valued as extremely versatile electrophilic intermediates. Control over the regioselectivity with which arynes react is typically achieved using comparatively simple and/or chemically inutile substituents close to the reactive triple bond. READ MORE