Search for dissertations about: "ion segregation"

Showing result 1 - 5 of 18 swedish dissertations containing the words ion segregation.

  1. 1. Ion Solvation in Critical Binary Aqueous Solvents Probed by Advanced Synchrotron-Based Techniques

    Author : Monika Witala; Göteborgs universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; preferential ion solvation; microscopic segregation of hydrophilic ions; ion size asymmetry; critical binary liquid mixtures; 2; 6-dimethylpyridine; potassium chloride; grazing-incidence x-ray fluorescence; small-angle x-ray scattering; mesoscale ordering; x-ray beam-induced local heating;

    Abstract : The Poisson-Boltzmann equation is the standard tool for studying the electrostatic interactions in electrolyte solutions, although it neglects e.g. the ion size and ion-ion correlations. Even experimentally observed specific ion effects cannot be explained in a view of this approximation. READ MORE

  2. 2. Microstructure of Nickel-Chromium Superalloys

    Author : Mattias Thuvander; Chalmers tekniska högskola; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; segregation; TEM; nickel alloy; grain boundary; APFIM; SIMS; carbide; precipitation; ordering; boride;

    Abstract : The microstructure of nickel-chromium superalloys has been investigated using several advanced microanalytical techniques; atom probe field ion microscopy (APFIM), transmission electron microscopy (TEM) together with energy dispersive X-ray analysis (EDX) and electron energy loss spectroscopy (EELS), secondary ion mass spectroscopy (SIMS) and optical microscopy (OM). The features primarily considered include precipitation, segregation and ordering. READ MORE

  3. 3. The anode and the electrolyte in the MCFC

    Author : Andreas Bodén; Göran Lindbergh; Carina Lagergren; Takao Watanabe; KTH; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; composite electrolytes; electrode kinetics; nickel solubility; porous electrode; reformate; water-gas shift reaction; electrolyte; electrolyte distribution; hydrogen oxidation reaction; ion segregation; mass transport; mathematical modelling; MCFC; molten carbonate fuel cell; Chemical engineering; Kemiteknik;

    Abstract : A goal of the Swedish government is to increase the usage of renewable fuels and biomass-based fuels. Fuel cells, and especially the MCFC, are useful for these types of fuels. The Swedish market may benefit from the MCFC in two ways: increased efficiency of the biofuels and also utilisation of produced heat in district heating. READ MORE

  4. 4. Weldability of Cast Superalloys - Effect of homogenization heat treatments on hot cracking susceptibility of cast Alloy 718, ATI® 718Plus®, and Haynes® 282®

    Author : Sukhdeep Singh; Chalmers tekniska högskola; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Hot ductility; Segregation; Homogenization; Boron; Gleeble; Welding; Nickel-based superalloys; Varestraint; Hot cracking; Hot isostatic pressing; Niobium;

    Abstract : Precipitation hardened Ni- and Ni–Fe-based superalloys are used in high-temperature sections of aero engines owing to their superior mechanical properties compared to those of the other alloys. However, their better mechanical performance is accompanied by its own challenges during the manufacturing process. READ MORE

  5. 5. Life and Death of Mixed Metal Halide Perovskites : Mechanism and Consequences of Light Induced Halide Segregation in MAPb(I,Br)3

    Author : Klara Suchan; NanoLund: Centre for Nanoscience; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; phase segregation; X-ray diffraction; perovskite; solar cells; photoluminescence;

    Abstract : Metal halide perovskites have attracted immense scientific interest due to their outstanding optoelectronic properties over a widebandgap range. Applications cover a wide range of optoelectronic devices from solar cells, LEDs and lasers to X-ray detectors. READ MORE