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Showing result 1 - 5 of 5994 swedish dissertations matching the above criteria.

  1. 1. Isotopes as Mechanism Spies : Nucleophilic Bimolecular Substitution and Monoamine Oxidase B Catalysed Amine Oxidation Probed with Heavy Atom Kinetic Isotope Effects

    Author : Susanna MacMillar; Olle Matsson; Anita Hussénius; Daniel M. Quinn; Uppsala universitet; []
    Keywords : Organic chemistry; nucleophilic bimolecular substitution SN2; kinetic isotope effects; precision conductometry; monoamine oxidase B MAO B; reaction mechanism; carbon 11C 14C kinetic isotope effect; ion pairing triple-ion formation; para-substituted benzyl chlorides; tetrabytylammonium cyanide; Organisk kemi;

    Abstract : This thesis concerns the study of reaction mechanisms by means of kinetic isotope effects (KIEs). Studies of the nucleophilic bimolecular substitution (SN2) reaction had the dual purpose of improving our fundamental understanding of molecular reactivity and assessing the ability of kinetic isotope effects to serve as mechanistic tools. READ MORE

  2. 2. Studies of the anomeric center : mechanism and synthesis

    Author : Karl-Jonas Johansson; Harri Lönnberg; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organic Chemistry; organisk kemi;

    Abstract : This thesis is based on three publications and one appendix and is divided into two parts. The first part is a mechanistic study of the anomerization reaction of both aldo and keto glycosides and the second part is a synthetic study of a unusual type of glycosidic linker found in the lipopolysaccharide core Proteus Mirabilis 0270. READ MORE

  3. 3. Modular mechatronic mechanism

    Author : Björn Möller; KTH; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Other engineering mechanics; Övrig teknisk mekanik;

    Abstract : .... READ MORE

  4. 4. Controlled Ring-Opening Polymerization : Mechanism and Synthesis of Macromolecular Architectures with Tailored Properties

    Author : Maria Ryner; KTH; []
    Keywords : controlled ring-opening polymerization; poly L-lactide ; poly 1; 5-dioxepan-2one ; stannous octoate; tin alkoxide; DFT methods; mechanism; triblock; multiblock; tailored hydrophilicity; elastomers; resorbable materials;

    Abstract : .... READ MORE

  5. 5. Micro-reaction Mechanism Study of the Biomass Thermal Conversion Process using Density Functional Theory

    Author : Xiaolei Zhang; Weihong Yang; Linda J. Broadbelt; KTH; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; biomass thermal conversion; cellulose pyrolysis; char steam gasification; adsorption; interaction; mechanism; quantum chemistry; density functional theory;

    Abstract : Biomass, or bio-energy, is one of the most important alternative energies because of environmental concerns and the future shortage of fossil fuels. Multi-scaled bioenergy studies have been performed in the division of Energy and Furnace Technology, which included studies of macroscopic systems such as systems and reactors, modeling of computational fluid dynamics (CFD), and atomic/molecular level studies. READ MORE