Search for dissertations about: "phosphine-substitution"

Found 1 swedish dissertation containing the word phosphine-substitution.

2. 1. Iron Carbonyl Clusters as Proton Reduction Catalysts

   Author : Ahibur Rahaman; Kemisk fysik; []
   Keywords : iron-only hydrogenase; phosphine-substitution; electrocatalysis; proton reduction;

   Abstract : Abstract – The mixed-valence triiron complexes [Fe3(CO)7-x(PPh3)x(µ-edt)2] (x = 0, 1, 2; edt = SCH2CH2S) and [Fe3(CO)5(κ2-diphosphine)(µ-edt)2] (diphosphine = dppv, dppe, dppb, dppn) have been prepared and structurally characterized. In comparison to the diiron complex [Fe2(CO)6(µ-edt)], [Fe3(CO)7(µ-edt)2] catalyzes proton reduction at 0. READ MORE