Search for dissertations about: "plasticizer poly butylene adipate"

Found 3 swedish dissertations containing the words plasticizer poly butylene adipate.

  1. 1. Poly (butylene succinate) and poly (butylene adipate) : quantitative determination of degradation products and application as PVC plasticizers

    Author : Annika Lindström; Minna Hakkarainen; Ann-Christine Albertsson; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Biochemistry; solid phase extraction; degradation products; poly butylene succinate ; poly butylene adipate ; GC-MS; PVC; plasticizer; Biokemi; Biochemistry; Biokemi;

    Abstract : A solid phase extraction (SPE) method was developed for simultaneous extraction of dicarboxylic acids and diols formed during hydrolysis of poly(butylene succinate), PBS, and poly(butylene adipate), PBA. The developed SPE method and subsequent GC-MS analysis were used to extract, identify and quantify low molecular weight products migrating from linear and branched poly(butylene adipate) (PBA) and poly(butylene succinate) (PBS) during aging in aqueous media. READ MORE

  2. 2. Environmentally Friendly Plasticizers for PVC : Improved Material Properties and Long-term Performance Through Plasticizer Design

    Author : Annika Lindström; Minna Hakkaraninen; Anders Södergård; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; poly butylene adipate ; poly vinyl chloride ; plasticizers; miscibility; mechanical properties; surface segregation; migration; degradation products; Polymer chemistry; Polymerkemi;

    Abstract : Linear and branched poly(butylene adipate) polyesters with number-average molecular weights ranging from 700 to 10 000 g/mol, and degrees of branching ranging from very low to hyperbranched were solution cast with PVC to study the effects of chemical structure, molecular weight, end-group functionality, and chain architecture on plasticizing efficiency and durability. Miscibility was evaluated by the existence of a single glass transition temperature and a shift of the carbonyl group absorption band. READ MORE

  3. 3. Functional PVC Additives : Core-Shell Nanoparticle and Renewable Resource Plasticizers

    Author : Bo Yin; Minna Hakkarainen; Mikael Skrifvars; KTH; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; PVC; nanocomposite; nanoparticle; core-shell; plasticizer; renewable resources; isosorbide; glucose;

    Abstract : Several functional poly(vinyl chloride) (PVC) additives were designed: PVC plasticizers made from renewable resources as alternatives to traditional phthalate plasticizers and core-shell nanoparticle-plasticizers with the aim to design an additive that can improve several mechanical properties simultaneously. Monomeric and oligomeric PVC plasticizers based of isosorbide and glucose were synthesized. READ MORE