Search for dissertations about: "porfyrin"

Showing result 1 - 5 of 10 swedish dissertations containing the word porfyrin.

  2. 1. Life of Excitons in Artificial Photosynthetic Antennas

    Author : Johan Andersson; Kemisk fysik; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Zn-porphyrin; Osmium; Ruthenium; Polypyridine; Inter Ligand Energy Transfer; Inter System Crossing; Excited state dynamics; Transition metal complexes; Photosynthetic Antennas; Solar energy conversion; Artificial photosynthesis; Physical chemistry; Fysikalisk kemi; Transient Absorption Anisotropy.; Reaction Center; Dendrimer; Energy Transfer;

    Abstract : Due to the predicted energy crisis when fossil fuels will be exhausted it is important to search for alternative energy sources. Utilizing sunlight via artificial photosynthesis is an interesting possibility. READ MORE

  4. 2. Molecular Trees for Collecting Sunshine -Monitoring and Controlling Energy Transfer in Dendrimers

    Author : Jane Larsen; Kemisk fysik; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; magnetiska och optiska ; supraledare; magnetisk resonans; egenskaper elektriska; Kondenserade materiens egenskaper:elektronstruktur; supraconductors; magnetic resonance; relaxation; spectroscopy; Condensed matter:electronic structure; electrical; magnetic and optical properties; Kemi; Chemistry; Femtosecond transient absorption; Os-Ru metal ligand complexes; Cu-porphyrin-appended dendrimers; Zn-porphyrin-appended dendrimers; Annihilation; Energy transfer; Solar energy conversion; Artificial photosynthesis; Antenna systems; spektroskopi; Physical chemistry; Fysikalisk kemi; Photochemistry; Fotokemi; Femtosecond fluorescence anisotropy;

    Abstract : A continuing use of fossil fuels will accelerate global warning and result in severe consequences for the environment and thereby also us. Development of alternative, sustainable and environmentally friendly energy sources is therefore crucial. One approach is to create an artificial photosynthetic system that converts sunshine into fuel (e.g. READ MORE

  5. 3. Hemoproteins of Enterococcus faecalis

    Author : Lena Frankenberg; Biologiska institutionen; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Växtekologi; heme Enterococcus faecalis enterococci catalase cytochrome; Plant ecology;

    Abstract : The gram-positive bacterium Enterococcus faecalis is a commensal organism, often found in the gut of humans and other animals. It can cause opportunistic disease and it frequently causes nosocomial infections. Treatment of such infections is often impaired by this organisms broad intrinsic and acquired resistance to antibiotics. E. READ MORE

  6. 4. Magnesium Chelatase: Insights into the first Step of Chlorophyll Biosynthesis

    Author : Nick Sirijovski; Biokemi och Strukturbiologi; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Electron microscopy; Proteobacteria; Mutants; Rhodobacter capsulatus; Tetrapyrrole; Plant biochemistry; Växtbiokemi; Biochemistry; Metabolism; Biokemi; metabolism; Proteins; enzymologi; enzymology; Proteiner; Chlorophyll biosynthesis; AAA proteins; Magnesium chelatase; Barley; ATPase;

    Abstract : The enzyme magnesium chelatase inserts magnesium into protoporphyrin IX (Proto) to produce to magnesium protoporphyrin IX, the first unique intermediate of the chlorophyll biosynthetic pathway. Magnesium chelatase is composed of three distinct proteins termed I (molecular weight ~40 kDa), D (~70 kDa) and H (~140 kDa). READ MORE

  7. 5. An Investigation of Peroxidase Activity in Biomimetic and Biological Systems

    Author : Ekaterina Ryabova; Kemiska institutionen; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; metabolism; Metabolism; enzymologi; Proteiner; enzymology; Proteins; hemoglobin; catalysis; peptide; peroxidase; protoporphyrin IX; Biokemi; Biochemistry;

    Abstract : In order to create a heme environment which permits biomimicry of heme-containing plant peroxidases and investigate the role played by the vinyl side chains of the porphyrin ring on the stability and, possibly, catalytic activity of model compounds, a number of new synthetic microperoxidases -– hemin-6(7)-gly-his methyl ester (HGH) and hemin-6(7)-gly-gly-his methyl ester (HGGH) and hemin-6,7-bis(gly-gly-his methyl ester) (H2GGH) as well as mesohemin-6(7)-gly-gly-his methyl ester (MGGH) and deuterohemin-6(7)-gly-gly-his methyl ester (DGGH) have been prepared by condensation of a peptide residue with the propionic side chains of hemin, mesohemin and deuterohemin, respectively. Reactivity studies towards different organic and inorganic substrates showed that not only five- but also six-coordinate hemin peptide complexes catalyze the oxidation of substrates by H2O2. READ MORE