Search for dissertations about: "tandem reactions"

Showing result 1 - 5 of 28 swedish dissertations containing the words tandem reactions.

  1. 1. Bisindoles : synthesis and reactions

    Author : Eva Koch; KTH; []
    Keywords : ;

    Abstract : In this thesis, synthesis of various bisindoles have beendeveloped.2,3-Bis-(3-indolyl) succinic acid derivatives wereobtained via iodine promoted coupling of the trianion ofindole-3-acetic acid (IAA) or from the dianion of themethylester of IAA. These compounds were converted to2,3-bis(3-indolyl) maleimides (arcyriarubin analogues) by DDQoxidation. READ MORE

  2. 2. Transition Metal-Catalyzed Redox Reactions : A Journey from Homogeneous Ruthenium to Heterogeneous Palladium Catalysis

    Author : Oscar Verho; Jan-Erling Bäckvall; Manfred Reetz; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; organisk kemi; Organic Chemistry;

    Abstract : The first part of the thesis covers the development and utilization of electronically modified (pentaarylcyclopentadienyl)Ru-complexes in the racemization of secondary alcohols. This study revealed that the electronic properties of the substrate were the main factors dictating whether β-hydride elimination or hydride re-addition becomes the rate-determining step of the racemization process. READ MORE

  3. 3. Building molecular complexity via tandem Ru-catalyzed reactions of allylic alcohols

    Author : Agnieszka Bartoszewicz; Belén Martín-Matute; Luke Pilarski; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Organisk kemi;

    Abstract : .... READ MORE

  4. 4. Discovery-Oriented Screening of Dynamic Systems: Combinatorial and Synthetic Applications

    Author : Marcus Angelin; Olof Ramström; Stefan Kubik; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; chemical education; crystallization; dynamic combinatorial chemistry; dynamic combinatorial resolution; dynamic system; enzyme catalysis; isoindolinone; lipase; nitroalcohol; nitroaldol reaction; phthalide; reversible; secondary alcohol; systems chemistry; tandem reaction; Organic chemistry; Organisk kemi; Bioorganic chemistry; Bioorganisk kemi;

    Abstract : This thesis is divided into six parts, all centered around the development of dynamic (i.e., reversibly interacting) systems of molecules and their applications in dynamic combinatorial chemistry (DCC) and organic synthesis. READ MORE

  5. 5. Development of Multi-Component Reactions using Catalytically Generated Allyl Metal Reagents

    Author : Nicklas Selander; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organic Chemistry; Organic chemistry; Organisk kemi;

    Abstract : This licentiate thesis is based on the development of catalytic reactions for the synthesis and application of organometallic reagents. By use of palladium pincer-complex catalysts, we have developed an efficient procedure for the synthesis of allylboronates starting from allylic alcohols. READ MORE