Search for dissertations about: "15N-1H-HMQC"

Found 1 swedish dissertation containing the word 15N-1H-HMQC.

2. 1. Aspects on the Regio and Stereo Selectivity in the Hydrolsilylation of 1,3-Dienes

   Author : Magnus Gustafsson; Centrum för analys och syntes; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; Metallorganisk kemi; Organometallic chemistry; Organisk kemi; Organic chemistry; Lewis acid; electrophilic ring closure; asymmetric hydrosilylation; reaction conditions; isoprene; regioselectivity; oxygen; Wilkinsons catalyst; 15N-1H-HMQC; 31P; heterobidentate ligands; catalyst; palladium; epoxy-allylsilanes; rhodium complexes; dienes;

   Abstract : This thesis is a summary of four papers concerning various aspects on the transition metal catalysed hydrosilylation of 1,3-dienes. The hydrosilylation reaction is formally an addition of a hydrosilane to an unsaturated system and depending on the reaction conditions, control of stereo-, regio-, and chemo-selectivity can be achieved. READ MORE