Search for dissertations about: "19F NMR"

Showing result 1 - 5 of 16 swedish dissertations containing the words 19F NMR.

  1. 1. Physico-Chemical Properties of Plant Polysaccharides Investigated with NMR Techniques

    Author : Åsa Östlund; Chalmers University of Technology; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NMR diffusometry; Dissolution of cellulose; Chemical shift imaging; Fiber hornification; Xylan; Molecular weight; Pore size distribution; Cryoporometry; Cellulose solution; 19F NMR; Gelation of cellulose; Self-diffusion; Pulsed field gradient NMR; TBAF DMSO; 1H NMR;

    Abstract : In the lead of developing new biomaterials from plant sources it is of importance to be able to control and vary the properties, such as flexibility, strength, and hygroscopicity of the final material. These properties are highly directed by the interactions between constituents on a molecular level. READ MORE

  2. 2. NMR Studies of Colloidal Systems in and out of Equilibrium

    Author : Pavel V. Yushmanov; Peter Stilbs; Terence Gosgrove; KTH; []
    Keywords : NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; stopped-flow NMR; temperature-jump NMR; crossrelaxation; NMR; NMR probe; fluorosurfactant; micellar kinetics; micellar structure; Physical chemistry; Fysikalisk kemi;

    Abstract : The Thesis describes (i) the development of add-on instrumentation extending the capabilities of conventional NMR spectrometers and (ii) the application of the designed equipments and techniques for investigating various colloidal systems. The new equipments are: Novel designs of stopped-flow and temperature–jump inserts intended for conventional Bruker wide-bore superconductive magnets. READ MORE

  3. 3. Pulsed Field Gradient NMR Studies of Diffusion in Polymer Gels

    Author : Diana Bernin; Chalmers University of Technology; []
    Keywords : diffusion; gel; alginate; pulsed field gradient NMR; 19F NMR; cellulose; 1H NMR; dendrimer; biomaterial; mass transport;

    Abstract : Soft biomaterials, such as gels, play an important role in different kinds of products and applications, in particular in drug delivery systems, health care products, and food. Polymer gel's great ability to control mass transport is applied on e.g. the uptake of liquids in diapers. READ MORE

  4. 4. Studies of protein structure, dynamics and protein-ligand interactions using NMR spectroscopy

    Author : Tobias Tengel; Göran Larsson; Maria Sunnerhagen; Umeå universitet; []
    Keywords : NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; 19F NMR; 2S albumin; PapD; protein-ligand interaction; structure; TFE; Yersinia; YopD; allergy; amphipathic helix; Ber e 1; Brazil nut; dynamics; FimC; LcrH; NMR screening; Biophysics; Biofysik;

    Abstract : In the first part of the thesis, protein-ligand interactions were investigated using the chaperone LcrH, from Yersinia as target protein. The structure of a peptide encompassing the amphipathic domain (residue 278-300) of the protein YopD from Yersinia was determined by NMR in 40% TFE. READ MORE

  5. 5. Solid-phase glycoconjugate synthesis : on-resin analysis with gel-phase ¹9F NMR spectroscopy

    Author : Mickael Mogemark; Umeå universitet; []
    Keywords : NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Solid-phase synthesis; protective groups; linkers; monitoring; gel-phase; 19F NMR spectroscopy; carbohydrates; oligosaccharides; glycopeptides; Organisk kemi; Organic chemistry; Organisk kemi;

    Abstract : An efficient and versatile non-destructive method to analyze the progress of solid-phase glycoconjugate synthesis with gel-phase 19F NMR spectroscopy is described. The method relies on use of fluorinated linkers and building blocks carrying fluorinated protective groups. READ MORE