Search for dissertations about: "Allylation"

Showing result 1 - 5 of 21 swedish dissertations containing the word Allylation.

  2. 1. Aromatic Allylation via Diazotization; Application in synthesis of heterocyclic compounds

    Author : Fredrik Ek; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Bengamide analogue.; parallel synthesis; trimethylsilyl azide; cycloaddition; imidazole; fused tetrazole derivatives; iodocyclization; benzazepine; tert-butyl nitrite; allylic bromide; aromatic allylation; diazotization; Organic chemistry; Organisk kemi;

    Abstract : A new method for allylation of aromatic systems has been developed. A number of arylamines were converted via diazotization to the corresponding allylaromatic compounds using tert-butyl nitrite and an excess of allylic bromides with complete regioselectivity. Electron-withdrawing groups, in the aromatic moiety, were necessary to obtain good yields. READ MORE

  4. 2. Lignin-Based Thermosets with Tunable Mechanical and Morphological Properties : A Study of Structure-Property Relationships

    Author : Iuliana Ribca; Mats Johansson; Martin Lawoko; Stephan V. Roth; Mika Sipponen; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; Softwood; hardwood; technical lignin; solvent fractionation; allylation; thiol-ene thermosets; thioether linkage; wide-angle X-ray scattering; π-π stacking interactions; Barrträ; lövträ; tekniskt lignin; lösningsmedelsfraktionering; allylering; tiol-en-härdplaster; tioeterbindning; vidvinkelröntgenspridning; π-π staplingsinteraktioner; Fiber- och polymervetenskap; Fibre and Polymer Science;

    Abstract : Nowadays, there is an urgent need to decrease our dependence on fossilresources and shift towards the use of renewable resources for advancingsustainable development. Utilizing renewable and bio-based raw materials,such as lignocellulosic biomass, for designing new materials is a promisingapproach to promote this objective. READ MORE

  5. 3. Development of Palladium-Catalyzed Transformations Involving η1-Allypalladium Species

    Author : Niclas Solin; Kálmán Szabó; Antonio M. Echavarren; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Palladium; Homogenous catalysis; Allylation; Electrophilic substitution; Density functional calculations; Organic chemistry; Organisk kemi;

    Abstract : This thesis is focused on investigation of the structure, reactivity and isomerization reactions of η1-allylpalladium complexes, which are key intermediates in catalytic transformations. The first part of this thesis concerns the structure and reactivity of bis-allylpalladium complexes. READ MORE

  6. 4. New Reactions with Allyl- and Allenylboron Reagents : Transition-Metal-Catalyzed and Transition-Metal-Free Carbon-Carbon Bond Formation Processes

    Author : Dong Wang; Kálmán J. Szabó; Jianbo Wang; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; carbon-carbon bond formation; cross-coupling; organoboron compound; allylboron reagent; allylation; transition metal; metal carbene; allenylboron reagent; transition metal free; diazo compound; tosylhydrazone; quinone; organisk kemi; Organic Chemistry;

    Abstract : Organoboron compounds have been widely used in carbon-carbon bond formation reactions in organic synthesis and catalysis. This thesis is focused on cross-coupling reactions of allyl-, allenylboronic acids and their ester derivatives via transition metal catalysis or transition-metal-free processes. READ MORE

  7. 5. Novel Pincer Complex-Catalyzed Transformations : Including Asymmetric Catalysis

    Author : Juhanes Aydin; Kálmán J. Szabó; Oleg V. Ozerov; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; pincer; palladium; catalysis; chiral; asymmetric; palladium IV; allylation; aldol; aminoacid; C-H functionalization; cross-coupling; homoallylic; heck reaction; tridentate ligand; Chemistry; Kemi; Organic Chemistry; organisk kemi;

    Abstract : This thesis is focused on the development of new pincer complex-catalyzed transformations. Optimization of the catalytic properties (fine-tuning) was directed to increase the catalytic activity as well as the chemo-, stereo- and enantioselectivity of the complexes. READ MORE