Search for dissertations about: "Benzyl Ethers"

Showing result 1 - 5 of 6 swedish dissertations containing the words Benzyl Ethers.

  2. 1. A Novel Rearrangement of Allyl Benzyl Ethers and Aspects on the Glyoxylate Ene Reaction

    Author : Johan Wennerberg; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; liverwort; natural product synthesis; phenyl butyraldehydes; allyl benzyl ethers; 2-hydride migration; 1; 4-rearrangement; regio selectivity; shape selectivity; zeolite; Ene reaction; Taxol A-ring; naphthalene derivatives; dihydronaphthalenes; Organic chemistry; Organisk kemi;

    Abstract : This thesis describes an improvement of the glyoxylate ene reaction by using siamyl glyoxaylate and a development of the novel rearrangement of allyl benzyl ethers. The glyoxylate ene reaction was used as a key reaction in a 8-step synthesis of a Taxol A-ring building block. READ MORE

  4. 2. Fundamental Aspects of Lignin Carbohydrate Complexes (LCC) : Mechanisms, Recalcitrance and Material concepts

    Author : Nicola Giummarella; Martin Lawoko; Gunnar Henriksson; Arthur J. Ragauskas; KTH; []
    Keywords : LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; Lignin Carbohydrates Complexes; Phenyl Glycosides; Benzyl Ethers; Benzyl and γ-esters; Universal Mild Quantitative fractionation; LCC mechanism formation; Extracellular lignin; Dehydogenation polymer; Autohydrolysis; Recalcitrance; Acetylation role; HSQC; HMBC; HSQC-TOCSY; 13C; 31P NMR; Thioacidolysis-GC; SEC; Green; Biomimetic; One-pot-lignin functionalization; Lignin platform material.; Fiber- och polymervetenskap; Fibre and Polymer Science;

    Abstract : Covalent bonds between lignin and carbohydrates, forming a matrix referred to as lignin carbohydrate complexes (LCC), remain one of the most controversial topics in wood chemistry. A key issue is whether they are formed during chemical and mechanical pretreatments of the compact wood structure or actually present in wood prior to isolation. READ MORE

  5. 3. Lignin-carbohydrate complexes: Model compounds synthesis

    Author : Filip Nylander; Chalmers tekniska högskola; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; Lignin-carbohydrate complex; lignin model compounds; lignocellulose;

    Abstract : In lignocellulose there is a recalcitrant interaction by covalent and non-covalent bonds called the lignin-carbohydrate complex. This interaction has been the subject of studies trying to unveil its chemical structure, to understand the mechanims involved in its formation and to determine its influence on practical applications such as the process of turning biomass into ethanol. READ MORE

  6. 4. Lewis acid promoted endocyclic cleavage of glycosides and related acetals

    Author : Roger Olsson; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; halichomycin; allylation; carbene; hydrogen bond; organozinc; organotitanium; furanosides; organoaluminium; pyranosides; glycosides; stereoselective; endocyclic cleavage; nucleophilic ring opening; ab initio; Organic chemistry; Organisk kemi;

    Abstract : This thesis is a summary of five papers concerning endocyclic cleavage of glycosides and related acetals. Simple lactol ethers undergo endocyclic cleavage to give acyclic chain extended products on treatment with organoaluminium and organotitanium reagents. READ MORE

  7. 5. Synthesis and Development of Methods for Preparation of Inositolphosphoglycans, Glycoglycerolipids and Glycerophospholipids

    Author : Jan Lindberg; Bertram Fraser-Reid; Linköpings universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES;

    Abstract : This thesis describes the synthesis of a series of myo-inositol-containing oligosaccharides, and the exploration of using the chiral epoxide (S)-glycidol in short synthetic routes to glycoglycerolipids and glycerophospholipids.In chapter 2, synthesis of the core heptasaccharyl myo-inositol Galp(α1-6)Galp(α1 -3)Galf(β1-3)[Glcp(α1-P04-6)Manp](α1-3)Manp(α1-4)GlcNp(α1-6)Ins-1-P04, found in the lipophosphoglycans of Leishmania parasites, is described. READ MORE