Search for dissertations about: "Caprolactone CL"

Showing result 1 - 5 of 18 swedish dissertations containing the words Caprolactone CL.

  1. 1. Novel methods to synthesize aliphatic polyesters of vivid architectures

    Author : Rajiv Srivastava; Ann-Christine Albertsson; Ronnie Palmgren; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Polyesters; 1; 5-dioxepan-2-one; Caprolactone; Sn Oct 2; Enzyme; Lipase-CA; Ring-Opening Polymerization; Architecture; Tissue Engineering; Polymer chemistry; Polymerkemi;

    Abstract : Cross-linked films of ε-caprolactone (CL) and 1,5-dioxepan-2-one (DXO) having various mole fractions of monomers and different cross-link densities were prepared using 2,2’-bis-(-caprolactone-4-yl) propane (BCP) as cross-linking agent and Sn(Oct)2 as catalyst. Reaction parameters were examined to optimize the film-forming conditions. READ MORE

  2. 2. Controlled Degradation of Polyester-Ethers Revealed by Mass Spectrometry Techniques

    Author : Anders Höglund; Ann-Christine Albertsson; Jukka Seppälä; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Degradation products; biocompatibility; -caprolactone; 1; 5-dioxepan-2-one; 6-hydroxyhexanoic acid; 3- 2-hydroxyethoxy propanoic acid; oligomers; Polymer chemistry; Polymerkemi;

    Abstract : The use of degradable biomedical materials in e.g. tissue engineering and controlled drug delivery has changed medical science during recent decades. The key question is to adapt the material with respect to mechanical properties, surface characteristics, and degradation profile to suit its intended application. READ MORE

  3. 3. Aliphatic Polyesters for Soft Tissue Engineering : Development from Conventional Organometallic to Novel Enzymatic Catalysis

    Author : Rajiv Kumar Srivastava; Ann-Christine Albertsson; Stanishaw Penzzek; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; aliphatic polyester; 1; 5-dioxepan-2-one; ε-caprolactone; L-lactide; D-lactide; D; L-lactide; enzyme; lipase CA; lipase PS; Polymer chemistry; Polymerkemi;

    Abstract : The development of macromolecules with defined structure and properties, aimed specifically for biomedical applications, has resulted in diverse biodegradable polymers with advanced architectures. Among them, aliphatic polyesters synthesized by ring-opening polymerization (ROP) of lactones and lactides have a leading position due to their good mechanical properties, hydrolyzability and biocompatibility. READ MORE

  4. 4. Controllable degradation product migration from biomedical polyester-ethers

    Author : Anders Höglund; Ann-Christine Albertsson; Lars Wågberg; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; degradation products; ε-caprolactone; 1; 5-dioxepan-2-one; 6-hydroxyhexanoic acid; 3- 2-hydroxyethoxy propanoic acid; cross-linking; inflammatory response; Polymer chemistry; Polymerkemi;

    Abstract : The use of degradable biomedical materials has during the past decades indeed modernized medical science, finding applications in e.g. tissue engineering and drug delivery. The key question is to adapt the material with respect to mechanical properties, surface characteristics and degradation profile to suit the specific application. READ MORE

  5. 5. Design of Functional Degradable Aliphatic Polyesters and Porous Tissue Engineering Scaffolds

    Author : Peter Plikk; Ann-Christine Albertsson; Marek Kowalczuk; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Ring-opening polymerization; Stannous octoate; 2; 2’-azoisobutyronitrile; 1; 5-dioxepane-2-one; ε-caprolactone; L-lactide; Trimethylene carbonate; 2-methylene-1; 3-dioxe-5-pene; Copolymer; Porous scaffold; Porous tubular scaffold; Electron beam; Gamma irradiation; Polymer chemistry; Polymerkemi;

    Abstract : The regeneration of damaged tissues or organs using porous scaffolds which act as temporary guides for the patient’s own cells, i.e. tissue engineering, is a means to overcome the shortcomings of current standard medical treatments. READ MORE