Search for dissertations about: "Chiral Auxiliary"

Showing result 1 - 5 of 13 swedish dissertations containing the words Chiral Auxiliary.

  2. 1. 1. Asymmetric aldol and alkylation reactions using pyrrolidine-based chiral auxiliaries 2. Syntheses of pine sawfly pheromone precursors and structurally related compounds

    Author : Fredrik Andersson; KTH; []
    Keywords : Chiral auxiliary; Stereoselectivity; Lewis acid; Aldol; Alkylation; Sex pheromone; Pine sawfly; Lipase; Synthesis; Diprion nipponica; Macrodiprion memoralis; Microdiprion pallipes; ;

    Abstract : This thesis describes the syntheses of the 1-propionylatedauxiliaries (S)-(− )-2-(pyrrolidin-2-yl)propan-2-ol and (S)-(− )-2-(1-methoxy-1-methylethyl)pyrrolidine andtheir use in asymmetric aldol and alkylation reactions. Thesynthesis of 1-propionylated (2S,4R) 2-{4-[(tert-butyldimethylsilyl)oxy]pyrrolidin-2-yl}propan-2-olis also described. READ MORE

  4. 2. 1. Asymmetric aldol and alkylation reactions using pyrrolidine-based chiral auxiliaries 2. Syntheses of pine sawfly pheromone precursors and structurally related compounds

    Author : Fredrik Andersson; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Chiral auxiliary; Stereoselectivity; Lewis acid; Aldol; Alkylation; Sex pheromone; Pine sawfly; Lipase; Synthesis; Chemistry; Kemi;

    Abstract : .... READ MORE

  5. 3. Green Chemistry in Chemical Education and Synthetic Applications of Sulfinamides

    Author : Björn Blomkvist; Peter Dinér; José Alemán; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Sulfinamide; Green Chemistry; Chiral Auxiliary; Photoredox; Teaching; Sulfinamid; Grön Kemi; Kiral Hjälpgrupp; Fotoredox; Undervisning; Kemi; Chemistry;

    Abstract : The preparation of chiral molecules, i.e. compounds that are not identical to their mirror image, is of great interest in the field of organic chemistry. READ MORE

  6. 4. Lewis acid Mediated Aza-Diels-Alder Reactions and Asymmetric Alkylations of 2H-azirines

    Author : Erik Risberg; KTH; []
    Keywords : Enantioselective; diastereoselective; vinyl azide; 2H-azirines; aziridines; Lewis acid; chiral ligand; chiral auxiliary organolithiums Diels-Alder reaction alkyl radicals triethylborane.;

    Abstract : This thesis describes the use of 2H-azirines, three-membered unsaturatednitrogen-containing heterocycles, as reactive intermediates ina number of Lewis acid promoted alkylations and Diels-Alderreactions providing synthetically useful aziridines. In order to carry out this investigation a new generalprocedure for the ring closure of vinyl azides, forming theresultant 3-substituted-2H-azirines, was developed applying low boiling solventsin closed reaction vessels at elevated temperatures. READ MORE

  7. 5. Organic Azides : Functional Molecules and Materials

    Author : Giampiero Proietti; Peter Dinér; Per I. Arvidsson; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; perfluorinated Aromatic Azide; Photoactivatable; fluorophores; aggregation-induced emission; sulfonimidamides; sulfoximes; chiral auxilary; organogel; azides reduction; Ni-B; Kemi; Chemistry;

    Abstract : The work presented in this thesis stems from the chemistry of the azido group, and more specifically from the unique reactivity of perfluorinated aromatic azides and how to use this reactivity to access new types of molecules to enable new applications in asymmetric synthesis and materials.In the first section of this thesis, a photoactivatable fluorescence probe is presented, where the non-luminescent azide was activated via a UV-light-promoted intramolecular N–H insertion reaction forming a fluorescence emitter. READ MORE