Search for dissertations about: "ETMS"

Showing result 1 - 5 of 7 swedish dissertations containing the word ETMS.

  2. 1. Aerobic Oxidative N-Heterocyclic Carbene Catalysis via Multistep Electron Transfer - Method Development and Applications

    Author : Anton Axelsson; Chalmers tekniska högskola; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; N-heterocyclic carbene; asymmetric synthesis; esterification; glycerol; electron transfer mediator; green chemistry; telescoped reaction; Organocatalysis; aerobic oxidation; dihydropyranone;

    Abstract : Oxidation reactions are ubiquitous in synthetic chemistry, but generally suffer from formation of large amounts of potentially toxic byproducts. Aerial oxygen represents an ideal oxidant since it is inexpensive, non-toxic and only forms water as a byproduct. READ MORE

  4. 2. Development of Biomimetic Catalytic Systems for Selective Oxidations with H2O2 and O2

    Author : Mikael Johansson; Jan-Erling Bäckvall; Matthias Beller; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Biomimetic oxidations; catalyst immobilization; dihydroxylation; sulfoxidation; flavin; Chemistry; Kemi; Organic Chemistry; organisk kemi;

    Abstract : Four different catalytic systems were studied for biomimetic coupled oxidations using H2O2 or O2. In the first example, osmium tetroxide works as a substrate-selective catalyst for dihydroxylation of olefins. Electron transfer to H2O2 is facilitated by electron transfer mediators (ETMs). READ MORE

  5. 3. Development of Aerobic Oxidative N-Heterocyclic Carbene Catalysis via Multistep Electron Transfer and its Application

    Author : Anton Axelsson; Chalmers tekniska högskola; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; dihydropyranone; Michael addition; kinetics.; aerobic oxidation; acylation; N-heterocyclic carbene; green chemistry; Organocatalysis; electron transfer mediator; asymmetric synthesis;

    Abstract : Oxidation reactions are ubiquitous in synthetic chemistry, but generally suffer from formation of large amounts of potentially toxic byproducts. Aerial oxygen represents an ideal oxidant since it is inexpensive, non-toxic and only forms water as a byproduct. READ MORE

  6. 4. Image dipoles and polarons in organic semiconductors

    Author : Yongzhen Chen; Mats Fahlman; Xianjie Liu; Yiqiang Zhan; Linköpings universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organic electronics; Interface dipole; Polaron; Conjugated polymer; Photoelectron spectroscopy; N-type doping; Electron transport material;

    Abstract : The rapid development of organic electronics depends on the synthesis of new π-conjugated molecules/polymers and the exploration of fundamental physics. However, most of the efforts have been concentrated on the former, leading to a lack of thorough understanding of many important concepts, which will become the ultimate limiting factor for overall performance and applications. READ MORE

  7. 5. Advances in Stereoselective Palladium(ΙΙ)-Catalyzed Oxidative Transformations of Allenes

    Author : Daniels Posevins; Jan-Erling Bäckvall; Troels Skrydstrup; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Synthesis; Palladium Catalysis; Allenes; Biomimetic; Carbocyclization; Borylation; Carbonylation; Oxidation; Heterogeneous; organisk kemi; Organic Chemistry;

    Abstract : Palladium(ΙΙ)-catalyzed carbon-carbon and carbon-heteroatom bond formation via selective C-H bond oxidation constitutes a step-economical and versatile approach towards complex target molecules. This thesis has been focused on the development of new selective palladium(ΙΙ)-catalyzed transformations of allenes under oxidative conditions catalyzed by either homogenous or heterogeneous palladium(ΙΙ) catalysts. READ MORE