Search for dissertations about: "Enantioselective synthesis"

Showing result 1 - 5 of 66 swedish dissertations containing the words Enantioselective synthesis.

  2. 1. Absolute Asymmetric Synthesis

    Author : Anders Lennartson; Göteborgs universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; absolute asymmetric synthesis; enantioselective synthesis; chirality; optical resolution; spontaneous resolution; conglomerate; organozinc reagents; organometallic chemistry; coordination chemistry; supramolecular chemistry; intermolecular interactions; optical resolution;

    Abstract : Absolute asymmetric synthesis is the synthesis of optically active products from achiral or racemic precursors only. This has generally been regarded as impossible and is relevant in the discussion of the origins of biomolecular homochirality. READ MORE

  4. 2. Toxicologically important DDT metabolites : Synthesis, enantioselective analysis and kinetics

    Author : Tatiana Cantillana; Åke Bergman; Peter Sundin; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; o; p -DDD; 3-Methylsulfonyl-DDE; adrenocorticolytic compounds; chiral; Environmental chemistry; Miljökemi; Environmental Chemistry; miljökemi;

    Abstract : DDT was extensively and globally used as a pesticide in agriculture and for malaria vector control from the 1940’s until the 1970’s. Due to its heavy use, DDT became ubiquitously distributed throughout the environment. DDT and several DDT metabolites are persistent organic pollutants. READ MORE

  5. 3. Lipase catalysed reactions of terpenoids : formation of hemiacetal esters : resolution of cryptone and its transformation to cadinenes

    Author : Dan Isaksson; Fredrik Almqvist; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; terpenoid; lipase; resolution; hemiacetal; hemiacetal ester; enantioselective; synthesis; cryptone; cadinene; Organic chemistry; Organisk kemi;

    Abstract : During attempted enzyme-catalysed resolution of sterically hindered secondary alcohols, hemiacetals and their esters were unexpectedly detected. Hemiacetal esters are reactive compounds that decompose to alcohol, aldehyde and acid under ordinary work-up conditions i.e. in contact with water, acid, or silica gel. READ MORE

  6. 4. Carbocation Catalysis for Organic Synthesis

    Author : Shengjun Ni; Johan Franzén; Bernd Plietker; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; carbocation; trityl cation; Lewis acid catalyst; enantioselective; chiral counteranion; oxa-Diels–Alder; bromination; aldehyde–olefin metathesis; Kemi; Chemistry;

    Abstract : The most common view of carbocations in organic chemistry is that they are short-lived intermediates in several fundamental reactions, e.g. the classic SN1-reaction. READ MORE

  7. 5. Enzyme- and Transition Metal-Catalyzed Asymmetric Transformations : Application of Enzymatic (D)KR in Enantioselective Synthesis

    Author : Richard Lihammar; Jan-Erling Bäckvall; Wolfgang Kroutil; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Dynamic Kinetic Resolution; Kinetic Resolution; Enzyme Catalysis; Asymmetric Synthesis; organisk kemi; Organic Chemistry;

    Abstract : Dynamic kinetic resolution (DKR) is a powerful method for obtaining compounds with high optical purity. The process relies on the combination of a kinetic resolution with an in situ racemization. READ MORE