Search for dissertations about: "MOF heterogeneous catalysis"

Showing result 1 - 5 of 8 swedish dissertations containing the words MOF heterogeneous catalysis.

  1. 1. Homogeneous and heterogeneous Cp*Ir(III) catalytic systems : Mechanistic studies of redox processes catalyzed by bifunctional iridium complexes, and synthesis of iridium-functionalized MOFs

    Author : Greco González Miera; Belén Martín-Matute; Matt Clarke; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; catalysis; bifunctional; metal-ligand cooperation; amine alkylation; Hammett; kinetics; acceptorless alcohol dehydrogenation; MOF; transition metal; synchrotron; organisk kemi; Organic Chemistry;

    Abstract : The purpose of this doctoral thesis is to investigate and develop catalytic processes mediated by iridium(III) complexes. By understanding the mechanisms, the weaknesses of the designed catalysts can be identified and be overcome in the following generation. READ MORE

  2. 2. Metal-Organic Frameworks (MOFs) for Heterogeneous Catalysis : Synthesis and Characterization

    Author : Mikaela Gustafsson; Xiaodong Zou; Pascal Van Der Voort; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; metal-organic frameworks; zeolitic imidazolate frameworks; functionalized linkers; structural transformation; heterogeneous catalysis; Structural Chemistry; strukturkemi;

    Abstract : Metal-organic frameworks (MOFs) are crystalline hybrid materials with interesting chemical and physical properties. This thesis is focused on the synthesis and characterization of different MOFs and their use in heterogeneous catalysis. READ MORE

  3. 3. Development of Metal–Organic Frameworks for Catalysis : Designing Functional and Porous Crystals

    Author : Fabian Carson; Xiaodong Zou; Jeffrey R. Long; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Metal–organic frameworks; heterogeneous catalysis; nanoparticles; metallolinkers; postsynthetic modification; postsynthetic exchange; Inorganic Chemistry; oorganisk kemi;

    Abstract : Metal–organic frameworks, or MOFs, have emerged as a new class of porous materials made by linking metal and organic units. The easy preparation, structural and functional tunability, ultrahigh porosity, and enormous surface areas of MOFs have led to them becoming one of the fastest growing fields in chemistry. READ MORE

  4. 4. Catalytic and Electrocatalytic Transformations with Palladium and Nickel : Scope and mechanistic investigations

    Author : Alejandro Valiente Sánchez; Belén Martín-Matute; King Kuok (Mimi) Hii; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organic Chemistry; Heterogeneous Catalysis; Metal-organic frameworks; Nickel; Palladium; Electrocatalysis; Cross-coupling; Hydrogenation; organisk kemi; Organic Chemistry;

    Abstract : The work presented in this thesis is based on methodology development and mechanistic investigations using heterogeneous palladium and nickel catalysts. Following the introduction (Chapter 1), Chapter 2 presents a summary of the synthesis and characterization of the MOF-supported Pd catalysts (Pd @ MOF) that are used in this thesis. READ MORE

  5. 5. Enols and Allylic Alcohols as Building Blocks in Synthetic Organic Chemistry : Experimental and Theoretical Studies

    Author : Alba Carretero Cerdán; Belén Martín‐Matute; Shu-Li You; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Base catalysis; Ion-pair; Isomerization; MOFs; Hypervalent Iodine III ; DFT; Organic Chemistry; organisk kemi;

    Abstract : The present thesis describes computational and experimental studies used to drive the reactivity of allylic and enol substrates towards new transformations. These synthetic methods give access to a number of organic molecules that may serve as important moieties in synthetic organic chemistry. READ MORE