Search for dissertations about: "O-O bond formation"
Showing result 1 - 5 of 15 swedish dissertations containing the words O-O bond formation.
-
1. Development of Ruthenium Catalysts for Water Oxidation
Abstract : An increasing global energy demand requires alternative fuel sources. A promising method is artificial photosynthesis. Although, the artificial processes are different from the natural photosynthetic process, the basic principles are the same, i.e. READ MORE
-
2. Mechanistic Insights into Transition Metal Oxide Catalyzed Water Oxidation
Abstract : A binuclear mechanism was proposed and evaluated by means of Density Functional Theory calculations. The central reaction steps were found to be the oxidation of the transition metal TM-OH moieties to TM=O and the subsequent intramolecular O-O bond formation between two TM=O groups. READ MORE
-
3. Challenges in Enzyme Catalysis - Photosystem II and Orotidine Decarboxylase : A Density Functional Theory Treatment
Abstract : Possibly the most fascinating biochemical mechanism remaining to be solved is the formation of oxygen from water in photosystem II. This is a critical part of the photosynthetic reaction that makes solar energy accessible to living organisms. READ MORE
-
4. Thiyl radicals, reaction kinetics and redox chemistry
Abstract : In focusing on the free radical chemistry of thiyl radicals,two importantclasses are dealt with, namely, the amino acidalkylthiyl and the acylthiyl radicals, where pulse radiolysisand steady state γ-radiolysis are applied.Amino acid thiyl radicals (RS•), are important in manybiological systems,as intermediates in the repair reactions ofthiols towards targeted carbon-centeredradicals and ascatalytic centers in many enzymatic reactions. READ MORE
-
5. Computational Studies on Homogeneous Water Oxidation Catalysts
Abstract : To combat the increasing energy demand and climate change, artificial photosynthesis is a promising approach to producing renewables by storing energy into chemicals and fuels. Water oxidation, responsible for offering electrons and protons to the reduction reactions, suffers from slow kinetics. READ MORE