Search for dissertations about: "OEC complex"

Found 5 swedish dissertations containing the words OEC complex.

  1. 1. Analysis of NMR Spin-lattice Relaxation Dispersion on Complex Systems

    Author : Yang Huang; Per-Olof Westlund; Arnold Maliniak; Umeå universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NMRD; relaxation theory; hydration; MD; FFC; PrxV; OEC complex; ZSM-5; BMIM [PF6; ]; fysikalisk kemi; Physical Chemistry;

    Abstract : This thesis focus on the analysis of spin-lattice NMRD relaxation profilesmeasured in various complex systems such as proteins, zeolites and ionicliquids. Proton, deuterium and fluoride T1-NMRD relaxation profiles wereobtained from a fast-field cycling (FFC) instrument. READ MORE

  2. 2. Molecular Approaches to Photochemical Solar Energy Conversion : Towards Synthetic Catalysts for Water Oxidation and Proton Reduction

    Author : Gerriet Eilers; Reiner Lomoth; Leif Hammarström; Wolfgang Lubitz; Uppsala universitet; []
    Keywords : Physical chemistry; artificial photosynthesis; solar fuel; WOC; OEC; accumulative electron transfer; hydrogenase mimic; oxygen evolution; proton reduction; water oxidation; Fysikalisk kemi;

    Abstract : A molecular system capable of photoinduced water splitting is an attractive approach to solar energy conversion. This thesis deals with the functional characterization of molecular building blocks for the three principal functions of such a molecular system: Photoinduced accumulative charge separation, catalytic water oxidation, and catalytic proton reduction. READ MORE

  3. 3. Effects of Protons and Small Alcohols on the Oxygen-Evolving Complex of Photosystem II

    Author : Paulina Geijer; Biokemi och Strukturbiologi; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; EPR; pH; methanol; S3; S2; S0; YZ; Mn cluster; Oxygen-evolving complex; S-states; Biochemistry; Metabolism; Biokemi; metabolism;

    Abstract : Higher plants and algae use oxygenic photosynthesis to convert solar energy to reducing equivalents and chemical energy. The ultimate electron donor to oxygenic photosynthesis is water. Oxidation of water to oxygen occurs in the oxygen-evolving complex (OEC) in Photosystem II (PSII). The OEC is composed of four Mn atoms, Ca2+ and Cl-. READ MORE

  4. 4. Photosynthetic Oxygen Evolution - EPR studies of the manganese cluster of photosystem II

    Author : Sindra Peterson Årsköld; Biokemi och Strukturbiologi; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; S2 state; second cycle; Biochemistry; Metabolism; Biokemi; metabolism; S0 state; light-adaptation; pulsed EPR; methanol; relaxation; microwave power saturation; S-cycle; Oxygen-evolving complex; Water-oxidizing complex;

    Abstract : In this thesis, a new electron paramagnetic resonance (EPR) signal from photosystem II is presented. The signal is shown to originate from the S0 oxidation state of the oxygen-evolving complex (OEC). READ MORE

  5. 5. Catalysts for Oxygen Production and Utilization : Closing the Oxygen Cycle: From Biomimetic Oxidation to Artificial Photosynthesis

    Author : Erik Karlsson; Jan-Erling Bäckvall; Björn Åkermark; Jerker Mårtensson; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; oxygen; catalytic oxidation; biomimetic oxidation; artificial photosynthesis; water oxidation; DFT calculations; Organic chemistry; Organisk kemi; organisk kemi; Organic Chemistry;

    Abstract : This thesis describes the development and study of catalysts for redox reactions, which either utilize oxygen or hydrogen peroxide for the purpose of selectively oxidizing organic substrates, or produce oxygen as the necessary byproduct in the production of hydrogen by artificial photosynthesis.The first chapter gives a general introduction about the use of environmentally friendly oxidants in the field of organic synthesis, and about the field of artificial photosynthesis. READ MORE