Search for dissertations about: "Organic catalysis"

Showing result 11 - 15 of 246 swedish dissertations containing the words Organic catalysis.

  1. 11. Mechanistic Studies on Ruthenium-Catalyzed Hydrogen Transfer Reactions

    Author : Jenny B. Åberg; Jan-Erling Bäckvall; Charles P. Casey; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; mechanistic studies; catalysis; ruthenium; hydrogen transfer; racemization; transfer hydrogenation; alcohols; ketones; amines; imines; inner-sphere; outer-sphere; solvent cage effect; Organic chemistry; Organisk kemi; organisk kemi; Organic Chemistry;

    Abstract : Mechanistic studies on three different ruthenium-based catalysts have been performed. The catalysts have in common that they have been employed in hydrogen transfer reactions involving alcohols and ketones, amines and imines or both. READ MORE

  2. 12. Palladium Catalysis in Directed C-H Bond Activation and Cycloisomerisation Reactions

    Author : Michael Oschmann; Jan-Erling Bäckvall; Oscar Verho; Jose Luis Mascareñas; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Palladium II ; Catalysis; C-H Functionalisation; Transamidation; XAS; organisk kemi; Organic Chemistry;

    Abstract : The main focus of this thesis concerns the development of Pd(II)-catalysed synthetic methodologies for the preparation of biologically active compounds.In the first part (paper I-III), unactivated C–H bonds of a cyclobutane derivative are selectively functionalised using a directing group starting from the feedstock compound verbenone (paper I). READ MORE

  3. 13. Coordination chemistry of late transition metals with PCP ligands. Synthesis, catalysis and mechanism

    Author : Daniel Olsson; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organometallic chemistry; Metallorganisk kemi; Organic chemistry; Oorganisk kemi; Inorganic chemistry; Suzuki reaction; Stille reaction; catalysis; cyclometalation; C-H activation; PCP complex; POCOP ligand; PCP ligand; iridium; palladium; platinum;

    Abstract : Abstract The work presented in this thesis discusses synthesis of PCP-complexes and utilisations of such organometallic compounds in catalysis. The complexes, obtained by intramolecular Csp3-H activation, are based on the metals palladium, platinum and iridium. READ MORE

  4. 14. Novel Pincer Complex-Catalyzed Transformations : Including Asymmetric Catalysis

    Author : Juhanes Aydin; Kálmán J. Szabó; Oleg V. Ozerov; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; pincer; palladium; catalysis; chiral; asymmetric; palladium IV; allylation; aldol; aminoacid; C-H functionalization; cross-coupling; homoallylic; heck reaction; tridentate ligand; Chemistry; Kemi; Organic Chemistry; organisk kemi;

    Abstract : This thesis is focused on the development of new pincer complex-catalyzed transformations. Optimization of the catalytic properties (fine-tuning) was directed to increase the catalytic activity as well as the chemo-, stereo- and enantioselectivity of the complexes. READ MORE

  5. 15. N-Heterocyclic Carbene Catalysis in Organic Synthesis - A Green Chemistry Approach

    Author : Linda Ta; Chalmers tekniska högskola; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; aerobic oxidation; ionic liquid; sustainability; NHC catalysis; oxidative NHC catalysis; green chemistry; OTHO; Organocatalysis;

    Abstract : The twelve principles of green chemistry were created as a response to the multiple environmental issues caused by the release of waste from the chemical industry. The principles acts as a guide in the development of sustainable chemical processes for the syntheses of important molecules needed to sustain our living standards. READ MORE