Search for dissertations about: "PCP."

Showing result 1 - 5 of 41 swedish dissertations containing the word PCP..

2. 1. Coordination chemistry of late transition metals with PCP ligands. Synthesis, catalysis and mechanism

   Author : Daniel Olsson; Centrum för analys och syntes; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organometallic chemistry; Metallorganisk kemi; Organic chemistry; Oorganisk kemi; Inorganic chemistry; Suzuki reaction; Stille reaction; catalysis; cyclometalation; C-H activation; PCP complex; POCOP ligand; PCP ligand; iridium; palladium; platinum;

   Abstract : Abstract The work presented in this thesis discusses synthesis of PCP-complexes and utilisations of such organometallic compounds in catalysis. The complexes, obtained by intramolecular Csp3-H activation, are based on the metals palladium, platinum and iridium. READ MORE

4. 2. Activation of CO2 by Palladium Complexes Bearing Tridentate PCP Ligands

   Author : Roger Johansson; Centrum för analys och syntes; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; Metallorganisk kemi; Organometallic chemistry; Kinetics; Insertion reactions; PCP ligands; CO2 activation; Palladium II complexes;

   Abstract : The present thesis deals with the activation of CO2 by insertion reactions into palladium-carbon bonds. This has been realised for the complexes {2,6-bis[(di-t-butylphosphino)methyl]benzene}palladium(II)methyl [(PCP)PdMe] and (PCP)PdCH2CHCH2. These complexes have also been used in the catalytic carboxylation of ZnMe2 and Bu3SnCH2CHCH2. READ MORE

5. 3. Functionalization and processing of porous powders into hierarchically porous monoliths

   Author : Petr Vasiliev; Lennart Bergström; Yoshio Sakka; Stockholms universitet; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; Porous; zeolite; hierarchical; monolith; nanoparticle; functionalization; amorphization; PCP; SPS; pulsed current processing; spark plasma sintering.; Chemistry; Kemi; Inorganic Chemistry; oorganisk kemi;

   Abstract : Inorganic porous materials are widely used in a number of applications, where is a need to functionalize and produce materials with a multiscale porosity. The first part of the thesis describes how a novel and facile powder processing approach, using pulsed current processing (PCP) or, as it is commonly called, spark plasma sintering (SPS), has been employed to produce mechanically stable, hierarchically porous bodies from different porous powders. READ MORE

6. 4. Hardness of Constraint Satisfaction and Hypergraph Coloring : Constructions of Probabilistically Checkable Proofs with Perfect Completeness

   Author : Sangxia Huang; Johan Håstad; Rishi Saket; KTH; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; Combinatorial optimization; approximation; inapproximability; hardness; probabilistically checkable proofs; pcp; perfect completeness; boolean constraint satisfaction problem; csp; graph coloring; hypergraph coloring; direct sum; superposition; label cover; Computer Science; Datalogi;

   Abstract : A Probabilistically Checkable Proof (PCP) of a mathematical statement is a proof written in a special manner that allows for efficient probabilistic verification. The celebrated PCP Theorem states that for every family of statements in NP, there is a probabilistic verification procedure that checks the validity of a PCP proof by reading only 3 bits from it. READ MORE

7. 5. Nickel and iridium pincer complexes with saturated frameworks - synthesis and reactivity

   Author : Klara Jonasson; Centrum för analys och syntes; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; PCP complexes; aliphatic pincer ligands; coordination; cyclometallation; iridium; nickel; organometallic synthesis; CO2 activation; catalysis;

   Abstract : As the tridentate chelate complexes referred to as pincer complexes have expanded their scope as homogeneous catalysts, there is an increased interest in electronic and steric fine-tuning of such complexes. One accessible variable in this aspect is the hybridisation of any coordinated carbon atoms. READ MORE