Advanced search

Showing result 1 - 5 of 111 swedish dissertations matching the above criteria.

2. 1. Novel Pincer Complex-Catalyzed Transformations : Including Asymmetric Catalysis

   Author : Juhanes Aydin; Kálmán J. Szabó; Oleg V. Ozerov; Stockholms universitet; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; pincer; palladium; catalysis; chiral; asymmetric; palladium IV; allylation; aldol; aminoacid; C-H functionalization; cross-coupling; homoallylic; heck reaction; tridentate ligand; Chemistry; Kemi; Organic Chemistry; organisk kemi;

   Abstract : This thesis is focused on the development of new pincer complex-catalyzed transformations. Optimization of the catalytic properties (fine-tuning) was directed to increase the catalytic activity as well as the chemo-, stereo- and enantioselectivity of the complexes. READ MORE

4. 2. Palladium(II)-Catalyzed Addition Reactions : Synthesis of Aryl Amidines and Aryl Ketones

   Author : Jonas Rydfjord; Mats Larhed; Adriaan Minnaard; Uppsala universitet; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; Palladium; Catalysis; Palladium II catalysis; Synthesis; Addition Reactions; Cyanamide; Amidine; Aryl Amidine; Nitrile; Ketone; Aryl Ketone; Carbopalladation; Continuous-flow; Continuous flow; Microwave heating; Farmaceutisk vetenskap; Pharmaceutical Science;

   Abstract : Palladium-catalyzed reactions have become one of the most important tools in modern organic chemistry due to its ability to catalyze the formation of new carbon-carbon bonds.The aim of the work presented in this thesis was to develop new palladium(II)-catalyzed addition reactions. READ MORE

5. 3. Palladium(II)-Catalysed Heck and Addition Reactions : Exploring Decarboxylative and Desulfitative Processes

   Author : Bobo Skillinghaug; Mats Larhed; Antonio de la Hoz Ayuso; Uppsala universitet; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; Palladium; catalysis; palladium II catalysis; synthesis; Heck; carboxylic acid; sulfinic acid; sodium sulfinate; nitrile; styrene; ketone; aryl ketone; electrospray ionization mass spectrometry; density functional theory; microwave heating; continuous flow; Chemistry with specialization in Organic Chemistry; Kemi med inriktning mot organisk kemi;

   Abstract : Palladium complexes have the ability to catalyse cross-coupling of two organic moieties through the formation of transient metal-carbon bonds, thus bringing them closer to each other to facilitate the formation of a new bond. Palladium-catalysed coupling reactions are one of the most important carbon-carbon forming reactions available to organic chemists and many of these reactions rely on the reactivity of aryl-palladium complexes. READ MORE

6. 4. Palladium-catalyzed lignin valorization : Towards a lignin-based biorefinery

   Author : Maxim Galkin; Joseph Samec; Rafael Luque; Uppsala universitet; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; LANTBRUKSVETENSKAPER; AGRICULTURAL SCIENCES; Lignin; Heterogeneous Catalysis; Palladium; Biomass; Depolymerization; Reduction; Oxidation; Biorefinery; Transfer Hydrogenolysis; Organic Chemistry; Organisk kemi;

   Abstract : The work described in this thesis focuses on the cleavage of the β-O-4′ bond, which is the most abundant interunit linkage in the lignin polymer.In the first part, three methods based on palladium catalysis have been developed and their applicability has been verified using lignin model compounds. READ MORE

7. 5. Coke on Supported Palladium and Platinum Catalysts

   Author : Mikael Larsson; Chalmers tekniska högskola; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; TPO; palladium; deactivation; coke; propane dehydrogenation; microbalance; vegetable oil hydrogenation; acetylene hydrogenation; catalysis; platinum;

   Abstract : Catalyst deactivation by coke formation has been investigated in three heterogeneous catalytic processes, propane dehydrogenation, acetylene hydrogenation and hydrogenation of vegetable oil. Palladium and/or platinum supported on alumina were used as catalysts in all reactions. READ MORE