Search for dissertations about: "Pulsed field gradient NMR"

Showing result 6 - 10 of 18 swedish dissertations containing the words Pulsed field gradient NMR.

  1. 6. NMR diffusion studies on lyotropic liquid crystalline systems

    Author : Greger Orädd; Frank Volke; Umeå universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Diffusion; pulsed field gradient; liquid crystalline systems; lipid lateral diffusion; cubic phases; peptide-lipid interactions; hydrophobic mismatch; permeability;

    Abstract : The pulsed field gradient fourier transform nuclear magnetic resonance (PFG-FTNMR) method to measure translational diffusion coefficients in multicomponent systems has been applied to amphiphilic molecules forming liquid crystalline phases.By analyzing the concentration dependence of the diffusion coefficients of water and amphiphile in a micellar system of N,N-dimethyldodecy lamine oxide (DDAO) in water it was possible to conclude that the micelles formed were polydisperse in size and shape. READ MORE

  2. 7. Nuclear Magnetic Relaxation Dispersion and Pulsed-Gradient Spin Echo Studies of Biomolecular Solutions and Amphiphilic Liquid Crystals

    Author : Haukur Jóhannesson; Biofysikalisk kemi; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; stretched dispersion; DNA hydration; solvent dynamics; NMRD; Random flight simulation; PGSE; Diffusion; Nematic phase; NMR; Amphiphilic liquid crystals; Physical chemistry; Fysikalisk kemi;

    Abstract : Biomolecular solutions and amphiphilic liquid crystals are studied by Nuclear Magnetic Resonance Dispersion (NMRD) and Pulsed-Gradient Spin Echo (PGSE) respectively. A random-flight simulation is performed to obtain the obstructing factors for self-diffusion of small molecules in macrofluids. READ MORE

  3. 8. Ionic lubricants : Molecular features and surface protection mechanisms

    Author : Bulat Munavirov; Sergei Glavatskih; Istvan Furo; Rob Dwyer-Joyce; KTH; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; ionic liquid; lubrication technology; tribology; boundary lubrication; tribofilm; friction; wear; physico-chemical interaction; diffusion NMR; jonisk vätska; smörjteknik; tribologi; gränsskiktssmörjning; tribofilm; friktion; slitage; fysikalisk-kemisk interaktion; NMR diffusometri; Machine Design; Maskinkonstruktion;

    Abstract : In this thesis ionic liquids (ILs) are investigated as prospective candidates for lubrication. Three custom synthesized phosphonium orthoborate type ILs were extensively studied from the prospective of molecular structuring both in bulk and at the interface and from the prospective of their lubricating performance as neat lubricants and as additives in oils. READ MORE

  4. 9. Generic Properties of Polymer Solutions

    Author : Takashi Uematsu; Chalmers tekniska högskola; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; photon correlation spectroscopy; collective diffusion; atomic force microscopy; relaxation; agarose gel electrophoresis; DNA; Zimm dynamics; pulsed-field gradient NMR; superdiffusion; polymer solution; blob model; gel;

    Abstract : Polymer solutions are abundantly present in our daily life, for example in paints, jellies, contact lenses and even in the living cells. Despite their ubiquity, we still have a poor understanding of the physical properties of solutions due to the extremely large number of internal degrees of freedom. READ MORE

  5. 10. NMR Diffusion Studies in Heterogeneous Systems. Surfactant solutions, Polymer solutions and Gels

    Author : Magnus Nydén; Fysikalisk kemi; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Physical chemistry; pfg nmr; polydispersity ehec ddas; polymer surfactant self-diffusion self-association heterogeneous media; Fysikalisk kemi;

    Abstract : The aim of this study has been to investigate the self-diffusion behaviour in polymer solutions and in surfactant solutions using the pulsed field gradient (PFG) NMR technique. The NMR self-diffusion experiment was shown to provide detailed information in complex surfactant mixtures. READ MORE