Search for dissertations about: "REAGENT"
Showing result 1 - 5 of 191 swedish dissertations containing the word REAGENT.
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1. Potential of Organosolv Lignin Nanoparticles as a Sustainable Flotation Reagent : Towards a Low-Carbon Footprint Mining Industry
Abstract : The green transition is driving a steep increase in the demand for minerals, which has put the focus on more responsible and sustainable mining practices as there is a growing pressure on mining operations to minimise their environmental footprint, mitigate risks in neighbouring communities, and decrease the consumption of natural resources. In 2022, mineral froth flotation was used to recover 18 million tonnes of copper from copper ore, accounting for 80% of total copper mine output. READ MORE
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2. New Reactions with Allyl- and Allenylboron Reagents : Transition-Metal-Catalyzed and Transition-Metal-Free Carbon-Carbon Bond Formation Processes
Abstract : Organoboron compounds have been widely used in carbon-carbon bond formation reactions in organic synthesis and catalysis. This thesis is focused on cross-coupling reactions of allyl-, allenylboronic acids and their ester derivatives via transition metal catalysis or transition-metal-free processes. READ MORE
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3. Novel Applications of Benziodoxole Reagents in the Synthesis of Organofluorine Compounds
Abstract : This thesis concerns method development of new synthetic routes by applying electrophilic hypervalent iodine reagents, such as trifluoromethyl-benziodoxole (Togni reagent) and fluoro-benziodoxole. The first project involved the addition of an oxygen moiety and trifluoromethyl group across double and triple bonds (both groups derived from the hypervalent iodine reagent). READ MORE
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4. Metal Mediated Synthesis. Synthetic and Mechanistic Investigations of Conjugate Addition and Reductive Amination
Abstract : The thesis is divided into two separate parts, one treating conjugate addition and the other reductive aminations. The first part of the thesis is concerned with organocopper promoted conjugate addition to .alfa.,. READ MORE
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5. Development and Applications of Hypervalent Iodine Compounds : Powerful Arylation and Oxidation Reagents
Abstract : The first part of this thesis describes the efficient synthesis of several hypervalent iodine(III) compounds. Electron-rich diaryliodonium salts have been synthesized in a one-pot procedure, employing mCPBA as the oxidant. Both symmetric and unsymmetric diaryliodonium tosylates can be isolated in high yields. READ MORE