Search for dissertations about: "Selective oxidation"

Showing result 21 - 25 of 128 swedish dissertations containing the words Selective oxidation.

  2. 21. Palladium(II)-Catalyzed Oxidative Carbocyclization/Functionalization of Allenynes

    Author : Teresa Bartholomeyzik; Jan-Erling Bäckvall; Diego J. Cárdenas; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; palladium catalysis; oxidation; carbocyclization; allenynes; boron reagents; kinetics; selectivity; reaction mechanism; organisk kemi; Organic Chemistry;

    Abstract : The selective formation of carbon-carbon bonds constitutes a key transformation in organic synthesis with useful applications in pharmaceutical or material industry. A particularly versatile tool for carbon-carbon as well as carbon-heteroatom bond formation is palladium catalysis, which allows for mild and selective routes even towards complex structures. READ MORE

  4. 22. Kinetics of Nanoparticle Catalysis from First Principles

    Author : Mikkel Jørgensen; Chalmers tekniska högskola; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; Density functional Theory; Mean field approximation; Acetylene hydrogenation; Kinetic Monte Carlo; CO oxidation; Entropy; Methane oxidation; Heterogeneous catalysis; Kinetic modeling; Nanoparticles;

    Abstract : Modern society depends heavily on heterogeneous catalysis, which creates strong economical and environmental incentives to improve catalyst efficiency. Heterogeneous catalysts are often realized as metal nanoparticles (NPs) supported on oxide surfaces, and catalysts are traditionally developed by trial and error approaches. READ MORE

  5. 23. Synthesis of Molecular Probes for Exploring the Human Consciousness, 5-HT7 Ligands and Salvinorins

    Author : Pär Holmberg; Anders Karlén; Adolf Gogoll; Anette Johansson; Christer Sahlberg; Uppsala universitet; []
    Keywords : MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; Pharmaceutical chemistry; serotonin system; opioid system; selective 5-HT7 agonist; 3-aminchromans; salvinorin A; selective kappa opioid receptor; mental disorders; consciousness; regioselective oxidation; enzymatic kinetic resolution; Farmaceutisk kemi; Pharmaceutical chemistry; Farmaceutisk kemi;

    Abstract : In this study, we have addressed the serotonergic and the opioid system within the CNS. Both systems are of outmost importance in the etiology of disease states, especially mental disorders. READ MORE

  6. 24. Oxidative Trifluoromethylation and other Functionalization Reactions of Alkenes and Alkynes

    Author : Pär Janson; Kálmán Szabó; Antonio Togni; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; palladium; copper; transition metal; trifluoromethylation; catalysis; acetoxylation; difunctionalization; oxidation; mechanistic study; alkenes; alkynes; quinones; organisk kemi; Organic Chemistry;

    Abstract : This thesis concerns the use of various potent oxidants in organic synthesis. The main focus is directed at selectively introducing trifluoromethyl groups into compounds containing double or triple bonds. All reactions proceed under mild conditions and can in most cases be performed on the bench-top. READ MORE

  7. 25. A Study of Propane and Propene Ammoxidation over Antimony-Vanadium-Oxide Catalysts at Steady-State and Transient Conditions

    Author : Roland Nilsson; Avdelningen för kemiteknik; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Kemiteknik och kemisk teknologi; Chemical technology and engineering; oxidation; Ammoxidation; propane; propene; propylene; catalysis; transient response; antimony vanadium oxides;

    Abstract : Propane ammoxidation catalysts of differing Sb/V ratio and consisting of differing amounts of the V2O5, alpha-Sb2O4, and Sb0.92V0.92O4 phases were prepared. In the first paper, the structure of Sb0. READ MORE