Search for dissertations about: "Stereoselective synthesis"

Showing result 6 - 10 of 63 swedish dissertations containing the words Stereoselective synthesis.

  2. 6. Stereoselective syntheses of semichemicals : Applications in ecological chemistry

    Author : Ellen M. Santangelo; Anna-Karin Borg-Karlsson; Olov Sterner; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; synthesis; semiochemical; pheromone; Lepidoptera; diene; Organisk kemi; Organic chemistry; Organisk kemi;

    Abstract : This thesis describes the syntheses of semiochemicals and their applications in the development of control methods for pest insects. The compounds synthesized are divided into three groups: 1) Lepidoptera pheromones; 2) methyl substituted chiral pheromones and 3) aphid pheromones. READ MORE

  4. 7. Synthesis of Organoboronic Acids and Applications in Asymmetric Organocatalysis

    Author : Sybrand Jonker; Kálmán Szabó; Jörg Pietruszka; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Boronic acid; BINOL; allylboration; propargylation; homologation; stereoselective synthesis; asymmetric synthesis; organocatalysis; allylboronic acid; allenylboronic acid; organisk kemi; Organic Chemistry;

    Abstract : Allyl- and allenylboronic acids are valuable reagents in organic synthesis due to their configurational stability and high reactivity. Few allyl- and allenylboronates are commercially available. Therefore, both the preparation and synthetic application of these organoboronic acids are subjects of study. READ MORE

  5. 8. Amino Aacohols : stereoselective synthesis and applications in diversity-oriented synthesis

    Author : Staffan Torssell; Peter Somfai; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; amino alcohol; carbenoid; carbonyl ylide; cross-metathesis; diastereoselective; 1; 3-dipolar cycloaddition; sphingosine; Organisk kemi; Organic chemistry; Organisk kemi;

    Abstract : This thesis is divided into three separate parts with amino alcohols as the common feature. The first part describes the development of a novel three-component approach to the synthesis of α-hydroxy-β-amino esters. READ MORE

  6. 9. Catalytic Stereoselective Formation of C–O, C–C and C–B Bonds : A Voyage from Asymmetric Reactions Enabled by Lipases to Stereoselective Palladium-Catalyzed Oxidative Transformations of Enallenes

    Author : Bin Yang; Jan Bäckvall; Matthias Beller; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Synthesis; Enzymatic kinetic resolution; Palladium; Allenes; Oxidative Transformations; Ruthenium; organisk kemi; Organic Chemistry;

    Abstract : This thesis has been focused on enzymatic kinetic resolutions and stereoselective oxidative transformations of enallenes catalyzed by PdII.In the first part of the thesis, a detailed discussion on Candida antarctica lipase B (CALB)-catalyzed kinetic resolution (KR) of δ-functionalized alkan-2-acetates is shown. READ MORE

  7. 10. Stereoselective Nucleophilic Additions to α-Amino Aldehydes: Application to Natural Product Synthesis

    Author : Per Restorp; Peter Somfai; Timothy J. Donohoe; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Stereoselective synthesis; Substrate-control; α-Amino aldehydes; Mukaiyama aldol; Allylsilanes; [3 2]-Annulation; -Alexine; DGDP; Vinyl epoxides; Regioselectivity; Alkyne nucleophiles; Organic chemistry; Organisk kemi;

    Abstract : This thesis deals with the development and application of new synthetic methodology for stereo- or regioselective construction of carbon-carbon bonds in organic synthesis. The first part of this thesis describes the development of a divergent protocol for stereoselective synthesis of chiral aminodiols by employing Mukaiyama aldol additions to syn- and anti-α-amino-β-silyloxy aldehydes. READ MORE