Search for dissertations about: "absolute asymmetric synthesis"
Showing result 1 - 5 of 9 swedish dissertations containing the words absolute asymmetric synthesis.
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1. Absolute Asymmetric Synthesis
Abstract : Absolute asymmetric synthesis is the synthesis of optically active products from achiral or racemic precursors only. This has generally been regarded as impossible and is relevant in the discussion of the origins of biomolecular homochirality. READ MORE
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2. Development of an Asymmetric Synthesis of Glionitrin A and B
Abstract : In this thesis, studies in the chemical synthesis of the dithiodiketopiperazine natural products (—)-glionitrin A and B are described.In Chapter 2, a synthesis of the indoline-fused 2,5-diketopiperazine core of glionitrin A and B using a C-H activation approach is described. READ MORE
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3. Homochiral crystals for selective synthesis
Abstract : Six new coordination compounds were prepared from monodentate sulfide ligands and copper(I) halides and their crystal structures were determined by single-crystal X-ray diffraction. The aim was to prepare coordination polymers that crystallize as conglomerates in order to use them in total spontaneous resolution. READ MORE
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4. Chiral Pyridine-Containing Ligands for Asymmetric Catalysis. Synthesis and Applications
Abstract : This thesis deals with the design and syntheses of chiral,enantiopure pyridinecontaining ligands and their applicationsin asymmetric catalyis.Chiral pyridyl pyrrolidine ligands and pyridyl oxazolineligands were synthesized and employed in thepalladium-catalysed allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate. READ MORE
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5. Biosynthetic and synthetic studies of the fungal metabolite galiellalactone
Abstract : Galiellalactone is a fungal metabolite found in the basidiomycetes Galiella rufa and the unidentified strain A111-95. It has been shown to possess promising activities as an inhibitor of the IL-6 mediated STAT3 signaling in HepG2 cells. READ MORE