Search for dissertations about: "allenylboronic acid"

Found 3 swedish dissertations containing the words allenylboronic acid.

  1. 1. Synthesis of Organoboronic Acids and Applications in Asymmetric Organocatalysis

    Author : Sybrand Jonker; Kálmán Szabó; Jörg Pietruszka; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Boronic acid; BINOL; allylboration; propargylation; homologation; stereoselective synthesis; asymmetric synthesis; organocatalysis; allylboronic acid; allenylboronic acid; organisk kemi; Organic Chemistry;

    Abstract : Allyl- and allenylboronic acids are valuable reagents in organic synthesis due to their configurational stability and high reactivity. Few allyl- and allenylboronates are commercially available. Therefore, both the preparation and synthetic application of these organoboronic acids are subjects of study. READ MORE

  2. 2. Synthesis of Organofluorine Compounds and Allenylboronic Acids - Applications Including Fluorine-18 Labelling

    Author : Denise N. Meyer; Kálmán J. Szabó; Dominique Cahard; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; NATURVETENSKAP; NATURAL SCIENCES; boron; allenylboronic acid; BINOL; homopropargyl alcohol; organocatalyst; organoboron; organofluorine; fluorine; fluorine-18; late-stage; labelling; labeling; nucleophilic; electrophilic; fluorination; positron emision tomography; PET; radiotracer; hypervalent iodine; benziodoxole; benzoxazepines; diaryliodonium salt; metal-free; neutrophil elastase; NE; neutrophil elastase inhibitor; trifluoromethylation; trifluoromethylthiolation; difluoro enol silyl ethers; organisk kemi; Organic Chemistry;

    Abstract : This work is focused on two areas: the chemistry of organofluorine and organoboron compounds. In the first chapter, a copper-catalysed synthesis of tri- and tetrasubstituted allenylboronic acids is presented. Extension of the same method leads to allenylboronic esters. READ MORE

  3. 3. New Reactions with Allyl- and Allenylboron Reagents : Transition-Metal-Catalyzed and Transition-Metal-Free Carbon-Carbon Bond Formation Processes

    Author : Dong Wang; Kálmán J. Szabó; Jianbo Wang; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; carbon-carbon bond formation; cross-coupling; organoboron compound; allylboron reagent; allylation; transition metal; metal carbene; allenylboron reagent; transition metal free; diazo compound; tosylhydrazone; quinone; organisk kemi; Organic Chemistry;

    Abstract : Organoboron compounds have been widely used in carbon-carbon bond formation reactions in organic synthesis and catalysis. This thesis is focused on cross-coupling reactions of allyl-, allenylboronic acids and their ester derivatives via transition metal catalysis or transition-metal-free processes. READ MORE