Search for dissertations about: "allyl"

Showing result 1 - 5 of 67 swedish dissertations containing the word allyl.

  2. 1. Synthesis and Rearrangement of Epoxy Sugars

    Author : Fritiof Pontén; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organisk kemi; Organic chemistry; crown ether; silica; Intramoleculaf Diels-Alder reaction; radical allylation; allyl sulfone; sugar epoxide; allyl sulfide; ring-contraction; C-glycoside; a; IMDAF; b-unsaturated aldehyde;

    Abstract : Ring-Contraction of sugar-derived epoxy alcohols, functionalised in position 1 and 6, by treatment with lithium bromide and N, N, N', N'-tetramethylurea in refluxing toluene gave enantiomerically pure a,b-unsaturated aldehydes of furanosides. O-Glycosidic epoxy alcohols gave only one, easily purified, aldehyde in approximately 30-60% yield depending on the substitution pattern. READ MORE

  4. 2. Regioselective reactions involving ( -Allyl)palladium intermediates : mechanistic studies and synthetic applications

    Author : Attila Aranyos; Uppsala universitet; []
    Keywords : NATURAL SCIENCES; NATURVETENSKAP;

    Abstract : .... READ MORE

  5. 3. Palladium catalyzed reactions involving -allyl intermediates : preparative and mechanistic aspects

    Author : Kenneth Granberg; Uppsala universitet; []
    Keywords : NATURAL SCIENCES; NATURVETENSKAP;

    Abstract : .... READ MORE

  6. 4. New Reactions with Allyl- and Allenylboron Reagents : Transition-Metal-Catalyzed and Transition-Metal-Free Carbon-Carbon Bond Formation Processes

    Author : Dong Wang; Kálmán J. Szabó; Jianbo Wang; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; carbon-carbon bond formation; cross-coupling; organoboron compound; allylboron reagent; allylation; transition metal; metal carbene; allenylboron reagent; transition metal free; diazo compound; tosylhydrazone; quinone; organisk kemi; Organic Chemistry;

    Abstract : Organoboron compounds have been widely used in carbon-carbon bond formation reactions in organic synthesis and catalysis. This thesis is focused on cross-coupling reactions of allyl-, allenylboronic acids and their ester derivatives via transition metal catalysis or transition-metal-free processes. READ MORE

  7. 5. A Novel Rearrangement of Allyl Benzyl Ethers and Aspects on the Glyoxylate Ene Reaction

    Author : Johan Wennerberg; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; liverwort; natural product synthesis; phenyl butyraldehydes; allyl benzyl ethers; 2-hydride migration; 1; 4-rearrangement; regio selectivity; shape selectivity; zeolite; Ene reaction; Taxol A-ring; naphthalene derivatives; dihydronaphthalenes; Organic chemistry; Organisk kemi;

    Abstract : This thesis describes an improvement of the glyoxylate ene reaction by using siamyl glyoxaylate and a development of the novel rearrangement of allyl benzyl ethers. The glyoxylate ene reaction was used as a key reaction in a 8-step synthesis of a Taxol A-ring building block. READ MORE