Search for dissertations about: "allylic alkylation"

Showing result 1 - 5 of 12 swedish dissertations containing the words allylic alkylation.

  1. 1. Ligand Dependent Regioselectivity in Palladium Mediated Allylic Alkylation

    Author : Charlotte Johansson; Göteborgs universitet; Göteborgs universitet; Gothenburg University; []
    Keywords : Palladium; allylic alkylation; η3-allyl palladium complexes; regioselectivity; PN-ligand; memory effects; dynamics; ligand effect; trans effects.;

    Abstract : In this thesis, different aspects on ligand dependent regioselectivity in palladium mediated allylic alkylation have been studied. It is believed that the regioselectivity is a result of nucleophilic attack trans to phosphorous when applying ligands wih different donor atoms. READ MORE

  2. 2. Chiral Pyridine-Containing Ligands for Asymmetric Catalysis. Synthesis and Applications

    Author : Fredrik Rahm; KTH; []
    Keywords : asymmetric catalysis; chiral ligand; chiral pool; oxazoline; crown ether; ditopic receptor; bipyridine; pyridyl alcohol; modular approach; P; N-ligand; diethylzinc; allylic alkylation;

    Abstract : This thesis deals with the design and syntheses of chiral,enantiopure pyridinecontaining ligands and their applicationsin asymmetric catalyis.Chiral pyridyl pyrrolidine ligands and pyridyl oxazolineligands were synthesized and employed in thepalladium-catalysed allylic alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate. READ MORE

  3. 3. Bispyridylamides as ligands in asymmetric catalysis

    Author : Oscar Belda de Lama; KTH; []
    Keywords : NATURAL SCIENCES; NATURVETENSKAP; asymmetric catalysis; chiral ligand; pyridine; amide; allylic alkylation; enantioselective; cyanation; ring-opening; chiral Lewis acid;

    Abstract : This thesis deals with the preparation and use of chiralbispyridylamides as ligands in metal-catalyzed asymmetricreactions. The compounds were prepared by amide formation usingdifferent coupling reagents. READ MORE

  4. 4. Studies of Hydrogenations and Isomerizations of Olefins and Alkylations of Amines Using Iridium Catalysts

    Author : Jia-Qi Li; Pher Andersson; Jianliang Xiao; Uppsala universitet; []
    Keywords : NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Iridium; Asymmetric; Hydrogenation; Isomerization; Alkylation; Organisk kemi; Organic Chemistry;

    Abstract : This thesis describes three types of reactions that were carried out using iridium catalysts.The first type is the iridium-catalyzed asymmetric hydrogenation of olefins. In paper I, the preparation of a new type of bicyclic thiazole-phosphine based iridium complex was described. READ MORE

  5. 5. Flexibility – a tool for chirality control in asymmetric catalysis

    Author : Raivis Zalubovskis; Christina Moberg; Alexandre Alexakis; KTH; []
    Keywords : NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; flexibility; symmetry; dissymmetry; asymmetric catalysis; chiral ligands; pseudo-C2; pseudo-CS; conformational study; rotation barrier; pyrrolidines; phospholanes; azepines; phosphepines; supramolecular; hydrogenation; allylic alkylation; silaboration; palladium; rhodium; nickel; platinum; iridium.; Organic chemistry; Organisk kemi;

    Abstract : This thesis deals with the design and synthesis of ligands for asymmetric catalysis: palladium catalyzed allylic alkylations, and rho-dium and iridium catalyzed hydrogenations of olefins. Chirally flexible phosphepine ligands based on biphenyl were synthesized and their properties were studied. READ MORE