Search for dissertations about: "aromatic substitution reaction"
Showing result 1 - 5 of 26 swedish dissertations containing the words aromatic substitution reaction.
-
1. Computer-Assisted Organic Synthesis. Addition to Carbonyl Carbons and Aromatic Substitution
Abstract : This thesis concerns the computer-assisted modelling of additions to ketones and aromatic substitution, and how this modelling can be used within an existing program for synthesis planning. I include a review of existing computer-assisted organic synthesis (CAOS) programs, and discuss how some of these programs deal with knowledge representation. READ MORE
-
2. On the mechanism of electrophilic aromatic substitution : an investigation by means of the effect of isotopic mass on reaction velocity
Abstract : .... READ MORE
-
3. Diaryliodonium Salts : Development of Synthetic Methodologies and α-Arylation of Enolates
Abstract : This thesis describes novel reaction protocols for the synthesis of diaryliodonium salts and also provides an insight to the mechanism of α-arylation of carbonyl compounds with diaryliodonium salts. The first chapter gives a general introduction to the field of hypervalent iodine chemistry, mainly focusing on recent developments and applications of diaryliodonium salts. READ MORE
-
4. Palladium-catalyzed aromatic coupling and allylic substitution
Abstract : Different types of palladium(II)-catalyzed aromatic couplingreactions have been investigated.The cyclization of diphenyl ether was found to be moresensitive to reaction conditions than was the cyclization ofthe diphenylamine derivatives. READ MORE
-
5. Quantum Chemical Studies of Aromatic Substitution Reactions
Abstract : In this thesis, density functional theory (DFT) is used to investigate the mechanisms and reactivities of electrophilic and nucleophilic aromatic substitution reactions (SEAr and SNAr respectively). For SEAr, the σ-complex intermediate is preceded by one (halogenation) or two (nitration) π-complex intermediates. READ MORE