Search for dissertations about: "chloride oxidation"

Showing result 1 - 5 of 48 swedish dissertations containing the words chloride oxidation.

2. 1. Electrochemical Reactions in Polymer Electrolyte Fuel Cells

   Author : Maria Wesselmark; Svein Sunde; KTH; []
   Keywords : ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; Fuel cell; model electrodes; oxygen reduction; methanol oxidation; formic acid oxidation; hydrogen oxidation; CO oxidation; degradation; tungsten oxide; carbon support; Bränslecell; modellelektroder; syrgasreduktion; metanoloxidation; myrsyraoxidation; vätgasoxidation; CO oxidation; degradering; wolfram oxid; kolsupport; Chemical engineering; Kemiteknik;

   Abstract : The polymer electrolyte fuel cell converts the chemical energy in a fuel, e.g. hydrogen or methanol, and oxygen into electrical energy. The high efficiency and the possibility to use fuel from renewable sources make them attractive as energy converters in future sustainable energy systems. READ MORE

4. 2. Structural, Electronic and Reactive Properties of Pentapyridyl - Base Metal Complexes : Relevance for Water Oxidation Catalysis

   Author : Manuel Boniolo; Johannes Messinger; Antoni Llobet; Uppsala universitet; []
   Keywords : NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; Water oxidation; Base metal complexes; Redox potential; Spin crossover; Magnetic anisotropy; Chemistry with specialization in Molecular Biomimetics; Kemi med inriktning mot molekylär biomimetik;

   Abstract : The rationalization of chemical-physical proprieties of transition metal complexes is fundamental in order to understand and tune their reactivity. In this thesis, a systematic investigation of the geometrical and electronic properties of [M(Py5OH)Cl]+ complexes (M= Mn, Fe, Co, Ni) has been performed, and their ability to act as molecular water oxidation catalysts has been probed. READ MORE

5. 3. Innovative process solutions towards recycling of salt cake from secondary aluminum smelting

   Author : Peng Li; Lidong Teng; Sankaran Subramanian; KTH; []
   Keywords : ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Thermal diffusivity; Model; Solubility; CO2; AlN; Crystals; Hydrolysis; Enhance; Hinder; Leaching; Absorption; Synthesis; SiMgAlON; Oxidation; Arctan; Activation energy; Mullite; Liquid; Crystallization.; SRA - Production; SRA - Produktion;

   Abstract : To offer better solutions for the recycling of salt cake from secondary aluminum melting, several innovative investigations were carried out based on hydrometallurgical and pyrometallurgical views.Thermal diffusivity measurements as a function of temperature on salts-Al composites having various compositions (0, 2, 4, 6, 8, 10, 12wt pct metallic Al) were carried out. READ MORE

6. 4. Chlorine Induced Corrosion in Biomass and Waste Fired Boilers: Laboratory and Field Investigations

   Author : Nicklas Folkeson; Chalmers University of Technology; []
   Keywords : NATURVETENSKAP; TEKNIK OCH TEKNOLOGIER; NATURAL SCIENCES; ENGINEERING AND TECHNOLOGY; austenitic; chloride; biomass; high temperature corrosion; ferritic; waste; steel;

   Abstract : The fireside corrosion in biomass and waste fired boilers is widely believed to arise from the presence of chlorine-containing compounds in the fuels. Although many researchers have studied the influence of such compounds on the high temperature corrosion of various steels, the mechanisms underlying chlorine-induced corrosion are still poorly understood. READ MORE

7. 5. Critical potential and oxygen evolution of the chlorate anode

   Author : Linda Nylén; Göran Lindbergh; Yohannes Kiros; KTH; []
   Keywords : ENGINEERING AND TECHNOLOGY; TEKNIK OCH TEKNOLOGIER; chlorate; chloride oxidation; oxygen evolution; critical anode potential; chromate; DSA; mass transport; RDE; Chemical engineering; Kemiteknik;

   Abstract : In the chlorate process, natural convection arises thanks to the hydrogen evolving cathode. This increases the mass transport of the different species in the chlorate electrolyte. There is a strong connection between mass transport and the kinetics of the electrode reactions. READ MORE