Search for dissertations about: "competitive Hammett study"

Found 2 swedish dissertations containing the words competitive Hammett study.

  2. 1. Iron or Copper? - Method Development and Mechanistic Studies on Cross-Coupling Reactions

    Author : Per-Fredrik Larsson; Göteborgs universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Iron; Copper; Transition metal; Cross-coupling; Reaction mechanism; Kinetic investigation; Hammett study; Sustainable catalysis; Trace-metal; Mass-transfer; Ligand development; Ligand scope;

    Abstract : The area of catalysis has had an immeasurable impact on modern society. This has been acknowledged through several Nobel prizes during the 20th century ranging from Haber (1918) for the synthesis of ammonia to Richard F. Heck, Ei-ichi Negishi, and Akira Suzuki (2010) for palladium-catalyzed cross-coupling reactions. READ MORE

  4. 2. Iron catalyzed C-C coupling reactions - mechanistic investigations

    Author : Anna Hedström; Göteborgs universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; iron; homogenous catalysis; cross coupling; C-C bond formation; reaction mechanisms; kinetic investigations; competitive Hammett study; density functional theory;

    Abstract : The mechanism of the iron catalyzed cross coupling of aryl electrophiles with alkyl Grignard reagents was studied. The reaction proceeds via a rate-limiting oxidative addition of the aryl halide to an Fe(I) complex generated in situ. A transmetalation from an aryl Grignard reagent occurs either before or after the oxidative addition. READ MORE