Search for dissertations about: "coordination polymers"

Showing result 1 - 5 of 21 swedish dissertations containing the words coordination polymers.

  2. 1. Homochiral crystals for selective synthesis

    Author : Theonitsa Kokoli; Göteborgs universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Absolute asymmetric synthesis; total spontaneous resolution; optical activity; coordination compounds; coordination polymers; photoisomerization; enantioselective sulfide oxidation; single crystal X-ray crystallography; co-crystallization of diastereomers;

    Abstract : Six new coordination compounds were prepared from monodentate sulfide ligands and copper(I) halides and their crystal structures were determined by single-crystal X-ray diffraction. The aim was to prepare coordination polymers that crystallize as conglomerates in order to use them in total spontaneous resolution. READ MORE

  4. 2. A molecular guide to efficient charge transport : Coordination materials for photovoltaic cells

    Author : Hannes Michaels; Marina Freitag; Aldo Di Carlo; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Coordination chemistry; energy conversion; photovoltaics; charge transport;

    Abstract : Emerging solar energy conversion and energy storage technologies play a vital role in solving the present energy crisis and achieving carbon net zero. Currently, they are limited by the use of inefficient, unstable and expensive charge transport materials. READ MORE

  5. 3. Cation Conduction and Coordination in Carbonyl-Containing Compounds : Li+ Transport in Alternative Polymer Electrolyte Host Materials

    Author : Therese Eriksson; Daniel Brandell; Jonas Mindemark; Claudio Gerbaldi; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Solid polymer electrolytes; Lithium ion batteries; Ion transport; Polyester; Polycarbonate; Polyketone; Ion coordination; Kemi med inriktning mot materialkemi; Chemistry with specialization in Materials Chemistry;

    Abstract : The field of solid polymer electrolytes (SPEs) used to create safer lithium-ion batteries has been dominated by polyethylene oxide (PEO) since the discovery of its ion-conducting properties in the 1970s. In this thesis, as an alternative, the ion coordination and conduction properties of SPEs based on polyketones, polyesters and polycarbonates are investigated. READ MORE

  6. 4. Using Molecular Dynamics Simulations to Explore Critical Property Relationships in Polymer Electrolytes : Polarity, Coordination, Ionic transport, Ion-pairing, and Ion-ion Correlations

    Author : Harish Gudla; Daniel Brandell; Chao Zhang; Andreas Heuer; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Solid polymer electrolytes; molecular dynamics simulations; solvent polarity; ion-pairing; ion coordination; ion transport mechanisms; Kemi med inriktning mot materialkemi; Chemistry with specialization in Materials Chemistry; Kemi med inriktning mot materialkemi; Chemistry with specialization in Materials Chemistry;

    Abstract : While ion transport in solid polymer electrolytes (SPEs) has been explored for decades, there still remains controversies about its fundamental properties, often correlated with gaps between experimental and computational studies. Using molecular dynamics simulations to understand the complex transport mechanisms and also to fill these gaps is the main goal of this thesis. READ MORE

  7. 5. Polymer Bound Water-Soluble Metal Phosphine Complexes-Preparation, Characterisation and Catalytic Application

    Author : Torsten Malmström; Kemiska institutionen; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; enantioselective; SAP; hydrogenation; hydroformylation; catalysis; biphasic; rhodium; poly-ethylene imine; poly-acrylic acid; polymers; water-soluble; phosphines; Inorganic chemistry; Oorganisk kemi;

    Abstract : Four new water-soluble phosphines have been prepared by utilising water-soluble polymers as charge carrying units. Coupling of methyl-4-(diphenylphosphino)-benzyl-amine or 4-diphenylphosphino benzaldehyde to poly-acrylic acid and poly-ethylene imine, respectively, afford the ligands PAA-PNH and PEI-PNH. READ MORE