Search for dissertations about: "enzymes Bioinorganic chemistry hydrolases models dinuclear heterodinuclear phosphotriesterase purple"

Found 1 swedish dissertation containing the words enzymes Bioinorganic chemistry hydrolases models dinuclear heterodinuclear phosphotriesterase purple.

2. 1. Dinuclear metal complexes modelling active sites of metallohydrolases

   Author : Martin Jarenmark; Kemisk fysik; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; Bioinorganic chemistry; enzymes; hydrolases; models; dinuclear; heterodinuclear; phosphotriesterase; purple acid phophatase;

   Abstract : To study the active sites of dinuclear metallohydrolases new metal complexes that model these sites both in structure and function have been synthesized using two new phenol based dinucleating ligands, 2-(N-isopropyl-N-((2-pyridyl)methyl)aminomethyl)-6-(N-(carboxylmethyl)-N-((2-pyridyl)methyl)aminomethyl)-4-methylphenol (IPCPMP) and 2,6-Bis[N-(N-(carboxymethyl)-N-(pyridylmethyl)amine)methyl]-4-methylphenolate (BCPMP). Both ligands contain pyridyl, tertiary amine and carboxylate groups but in IPCPMP one carboxylate donor is exchanged for a non-coordinating group yielding an unsymmetric ligand while BCPMP is symmetric with identical sets of ligands on either side of the phenol group. READ MORE