Search for dissertations about: "ethylenehalonium ions"

Found 1 swedish dissertation containing the words ethylenehalonium ions.

2. 1. Symmetry of Halonium Complexes in Solution

   Author : Anna-Carin Carlsson; Göteborgs universitet; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; bis pyridine -based halonium complexes; ethylenehalonium ions; structure symmetry; isotopic perturbation of equilibrium; solution NMR spectroscopy; isotope effects; N-X -N halogen bond; C-X -C interaction;

   Abstract : In this thesis the symmetry of two interaction types involving electropositive halogens have been studied in solution; the N-X+-N halogen bond (X = Br or I), and the C-X+-C interaction of previously characterised, cyclic, 1,2-bridged halonium ions (X = Cl or Br), respectively. The three N-X+-N model structures included are bispyridine, 1,2-bis(pyridine-2-ylethynyl)benzene and 1,2-bis((4-methylpyridin-2-yl)ethynyl)benzene halonium triflate complexes. READ MORE