Search for dissertations about: "fluorene"

Showing result 1 - 5 of 19 swedish dissertations containing the word fluorene.

  2. 1. Synthesis of bioactive natural products and analogues

    Author : Dan Killander; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; SAR; natural product; total synthesis; benzochromene; fluorene; cannabinoid; statin; TRPA1; TSLP; antiprotozoal; nociception; asthma; inflammation;

    Abstract : Natural products have until recently provided the only remedy for treatment of diseases. The development of modern chemistry in the last centuries has opened the door for tapping into the chemical diversity found in nature. Synthetic natural products, together with analogues, are an important piece in the puzzle towards curing many ailments. READ MORE

  4. 2. Functional and Modular As=C and P=C Group Motifs

    Author : Daniel Morales Salazar; Andreas Orthaber; Jose Goicoechea; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; materials; physical chemistry; arsaalkenes; phosphaalkenes; DBU; fluorene; photochemistry; arsenic; phosphorus; carbon; hydrogen; sulfur; gold; copper; organic materials; organic electronics; molecular electronics; polymers; transition metal complexes; molecular materials; small molecule; hydrogen bonding; electrochemistry; cyclic voltammetry; chronoamperometry; electropolymerization; artificial intelligence; potentiodynamic; modularity; functionality; XPS; DFT; π-conjugation effects; 2D-NMR; disilenes; siliconoids; group motifs; functional group; emergence; reactivity; reactive systems; organometallic complexes; π-delocalization; low-coordinate; main group chemistry; heavy p-block elements; pnictogens; copper I complex; gold I complex; photosensitizer; XRD; spectroelectrochemistry; electrochromism; smart materials; synthesis; phosphaalkene ligands; imine ligands; hysteresis-like criteria; representative settings; optimal criteria; transient covalence; interactive image; conformer; isomer; ligand scrambling; nanomaterials; stimuli-responsive; optical properties; ligand design; molecular design; X-ray crystallography; emission; self-assembly; As=C; Si=Si; P=C; multiple bond; equilibrium; heteroalkenes; alkenes; reversibility; Raman; ATR-FTIR; ERDA; Kemi; Chemistry;

    Abstract : This work focuses on the design, synthesis, characterization, and application projections of low-coordinated heavy pnictogen-containing (described by the generic letter E, hence E=C) phosphaalkenes (P=C) and arsaalkenes (As=C), with emphasis on the E=C group motifs. The work aims to understand their functional and modular character, reactivity, and potential applications by stabilizing, isolating, and characterizing these species in low-coordination environments. READ MORE

  5. 3. Quaternized fluorene-based hydroxide exchange membranes and polymers: design, synthesis, and characterization

    Author : Andrit Allushi; Centrum för analys och syntes; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; anion exchange membrane; hydroxide conductivity; alkaline stability; water electrolyzer; fuel cell;

    Abstract : In modern society, the consumption of fossil fuels has been increasing drastically, leading to significant emissions of carbondioxide (CO2), air pollution, global warming, and political and economic imbalances. This has increased the interest inrenewable and sustainable energy sources such as wind- and hydropower, solar energy, and in energy conversion by fuel celltechnology, and water electrolyses. READ MORE

  6. 4. Organic Hole-Transport Materials for Perovskite Solar Cells

    Author : Linqin Wang; Licheng Sun; Nam-Gyu Park; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Hole-transport material; Photovoltaic device; Perovskite solar cell; Dopant-free; Carbazole; Spiro[fluorene-9; 9 -xanthene]; Small organic molecule; Crosslinked polymer; Solution-processed.; Kemi; Chemistry;

    Abstract : Research on perovskite solar cells (PSCs) has undergone dramatic development since the first cells were reported in 2009, and the past decade has witnessed a significant breakthrough on their power conversion efficiencies (PCEs) from 3.8% to 25%. READ MORE

  7. 5. Mechanisms for Solvolytic Elimination and Substitution Reactions Involving Short-lived Carbocation Intermediates

    Author : Xiaofeng Zeng; Einar Uggerud; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; Organisk kemi; Organic chemistry; Organisk kemi; organisk kemi; Organic Chemistry;

    Abstract : Solvolysis reactions of a range of tertiary substrates in largely aqueous solvents were studied in such respects as β-deuterium kinetic isotope effects, linear free energy relationships and stereochemistry.Solvolysis of the fluorene derivatives 9-methyl–9-(2´-X-2´-propyl)fluorene (1-X, X = Cl, Br, OOCCF3) involves a very short-lived carbocation intermediate. READ MORE