Search for dissertations about: "fluxional behavior polynuclear metal complexes cluster thioether phosphine crystal structure sulfur"

Found 1 swedish dissertation containing the words fluxional behavior polynuclear metal complexes cluster thioether phosphine crystal structure sulfur.

2. 1. Coordination of Phosphine-Thioether Ligands to Low-valent Metal Centers

   Author : Roger Persson; Kemisk fysik; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; polynuclear metal complexes; fluxional behavior; cluster; thioether; phosphine; crystal structure; sulfur; triosmium;

   Abstract : The reactivity of the phosphine-thioether ligands bis(2-diphenylphosphino) ethylthio)ethane (PSSP), bis(2-(diphenylphosphino) ethyl)sulfane (PSP), PPh2CH2CH2SMe (PS), PPh2(o-C6H4SMe (PortoS), and PPh(o-C6H4SMe)2 (PSS) towards low-valent carbonyl clusters has been studied. In all structurally characterized clusters, the ligand donor atoms are terminally coordinated. READ MORE