Search for dissertations about: "heterocyclic chemistry"

Showing result 41 - 45 of 50 swedish dissertations containing the words heterocyclic chemistry.

  2. 41. Binary mixtures and cationic modification of protic ionic liquids. Local structure and transport properties

    Author : Iqbaal Abdurrokhman; Chalmers tekniska högskola; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; nuclear magnetic spectroscopy; cationic modification; triazolium; imidazolium; proton mobility; Protic ionic liquids; vibrational spectroscopy; impedance spectroscopy; binary mixtures; synthesis;

    Abstract : Protic ionic liquids are a subclass of ionic liquids, which in many cases are obtained by mixing an equimolar amount of Brønsted acid and base. Protic ionic liquids possess an exchangeable proton that gives them distinct features, e.g. READ MORE

  4. 42. Groove-binding Unsymmetrical Cyanine Dyes for DNA Applications

    Author : Maja Eriksson; Chalmers tekniska högskola; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; polarized spectroscopy; bacteriophage T5; cryo-transmission electron microscopy; dynamic light scattering; DNA; intercalation; cyanine dyes; groove-binding; fluorescence spectroscopy; gel electrophoresis;

    Abstract : This work focuses on interactions between DNA and a group of newly developed unsymmetrical cyanine dyes. The aim of the work was to discover fluorescent dyes that can be used in biophysical studies of natural DNA where minimum perturbation of the DNA-helix is essential, where a slow dissociation rate of the dyes is needed and where the ionic strength is an important parameter. READ MORE

  5. 43. Synthesis of heterocycles from anthranilic acid and its derivatives

    Author : Per Wiklund; Jan Bergman; Norbert de Kimpe; Södertörns högskola; Karolinska Institutet; Karolinska Institutet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Anthranilic acid; synthesis; heterocycles; benzodiazepines; HNO nitrosyl ;

    Abstract : Anthranilic acid (2-aminobenzoic acid, Aa) is the biochemical precursor to the amino acid tryptophan, as well as a catabolic product of tryptophan in animals. It is also integrated into many alkaloids isolated from plants. Aa is produced industrially for production of dyestuffs and pharmaceuticals. READ MORE

  6. 44. Silaborations of Unsaturated Compounds

    Author : Martin Gerdin; Christina Moberg; Kálmán Szabó; KTH; []
    Keywords : MEDICIN OCH HÄLSOVETENSKAP; MEDICAL AND HEALTH SCIENCES; allylboration; bismetallation; boron; carbocyclization; catalysis; 1; 3-diene; enantioselective; 1; 6-enyne; interelement; N-heterocyclic carbene; nickel; palladium; phosphine; phosphoramidite; platinum; reaction mechanism; silaboration; silicon; silylborane; stereoselective; Chemistry; Kemi;

    Abstract : This thesis deals with the development of transition metal-catalyzed silaborations of 1,3-dienes and 1,6-enynes. The first part of the thesis describes the development of the enantioselective 1,4-silaboration of 1,3-cyclohexadiene. A number of chiral metal-ligand complexes were evaluated. READ MORE

  7. 45. Ruthenium-catalyzed redox reactions and lipase-catalyzed asymmetric transformations of alcohols

    Author : Michaela Edin; Jan-E. Bäckvall; Manfred T. Reetz; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; ruthenium; lipase; catalysis; alcohols; diols; Chemistry; Kemi;

    Abstract : The major part of this thesis describes the synthesis of enantiopure alcohols and diols by combining ruthenium-catalyzed redox reactions that lead to racemization or epimerization and lipase-catalyzed asymmetric trans-formations in one-pot.A mechanistic study of the unexpected facile formation of meso-diacetate products found in enzyme-catalyzed acetylations of alkanediols with Candida antarctica lipase B (CALB) was first performed. READ MORE