Search for dissertations about: "linear free energy relationship"
Showing result 1 - 5 of 17 swedish dissertations containing the words linear free energy relationship.
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1. Concerted or Stepwise? : β-Elimination, Nucleophilic Substitution, Copper Catalysed Aziridination and Ruthenium Catalysed Transfer Hydrogenation Studied by Kinetic Isotope Effects and Linear Free-Energy Relationships
Abstract : This thesis describes the use of kinetic isotope effects, linear free energy relationships and stereochamical studies to distinguish between different mechanistic alternatives and to obtain information about transition state structure.In the first part fluorine and deuterium kinetic isotope effects were determined for the base promoted HF elimination from 4-fluoro-4-(4’-nitrophenyl)butane-2-on. READ MORE
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2. A Low-Leakage Linear Transverse-Flux Machine for a Free-Piston Generator
Abstract : The presented work is about a new low-leakage lineartransverse-flux electrical machine.The machine is dimensionedfor a free-piston generator. The intended application is inseries-hybrid vehicles. The free-piston generator is anintegration of a free-piston combustion engine with a linearelectrical machine. READ MORE
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3. Efficient Execution Paradigms for Parallel Heterogeneous Architectures
Abstract : This thesis proposes novel, efficient execution-paradigms for parallel heterogeneous architectures. The end of Dennard scaling is threatening the effectiveness of DVFS in future nodes; therefore, new execution paradigms are required to exploit the non-linear relationship between performance and energy efficiency of memory-bound application-regions. READ MORE
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4. Structure-Reactivity Correlations for Reactions of Palladium(II) and Platinum(IV) Complexes
Abstract : The kinetics and mechanism for substitution reactions on tetraaquapalladium(II) by an extended series of thioethers, a great number of carboxylic acids, and olefins have been studied by use of UV-VIS, stopped-flow, and high-pressure stopped-flow spectrophotometry and NMR spectroscopy. Second-order rate constants k and activation parameters (activation enthalpies, entropies, and volumes) for formation of monodentate 1:1 complexes have been determined. READ MORE
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5. Fundamental investigation to improve the quality of cold mix asphalt
Abstract : Cold mix asphalt (CMA) emulsion technology could become an attractive option for the road industry as it offers lower startup and equipment installation costs, energy consumption and environmental impact than traditional alternatives. The adhesion between bitumen and aggregates is influenced by diverse parameters, such as changes in surface free energies of the binder and aggregates or the presence of moisture or dust on the surface of aggregates, mixing temperatures, surface textures (including open porosity), nature of the minerals present and their surface chemical composition, as well as additives in the binder phase. READ MORE