Search for dissertations about: "linear free energy relationships LFER"

Found 2 swedish dissertations containing the words linear free energy relationships LFER.

  1. 1. Structure and Dynamics of Core-Excited Species

    Author : Oksana Travnikova; Maria Novella Piancastelli; Svante Svensson; Denis Ceolin; Pascal Lablanqui; Uppsala universitet; []
    Keywords : Physics; Synchrotron radiation; X-ray Photoelectron Spectroscopy XPS ; X-ray Absorption Spectroscopy XAS ; Resonant Auger Spectroscopy RAS ; Auger Electron Spectroscopy AES ; Energy-Selected Auger Electron PhotoIon COincidence ES-AEPICO ; core excitation; core ionization; linear free energy relationships LFER ; molecular-field splitting; substituent effects; nuclear dynamics; isomerization; Cl2; N2O; methane derivatives; allene; acetylacetone; Fysik;

    Abstract : In this thesis we have performed core-electron spectroscopy studies of gas phase molecular systems starting with smaller diatomic, continuing with triatomic and extending our research to more complex polyatomic ones. We can subdivide the results presented here into two categories: the first one focusing on electronic fine structure and effect of the chemical bonds on molecular core-levels and the other one dealing with nuclear dynamics induced by creation of a core hole. READ MORE

  2. 2. Partitioning and persistence of volatile methylsiloxanes in aquatic environments

    Author : Dimitrios Panagopoulos; Matthew MacLeod; Annika Jahnke; Amelie Kierkegaard; Whelan Mick; Stockholms universitet; []
    Keywords : NATURAL SCIENCES; NATURVETENSKAP; NATURVETENSKAP; NATURAL SCIENCES; siloxanes; organic carbon; sediment; partitioning; persistence; Applied Environmental Science; tillämpad miljövetenskap;

    Abstract : The presence of volatile methylsiloxanes (VMS) in the environment has raised concerns among environmental chemists and regulators about their persistence and the risks they may pose to the environment. This thesis explores the partitioning and persistence of VMS in aquatic environments. READ MORE