Search for dissertations about: "lipase B"
Showing result 11 - 15 of 73 swedish dissertations containing the words lipase B.
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11. Ruthenium-catalyzed redox reactions and lipase-catalyzed asymmetric transformations of alcohols
Abstract : The major part of this thesis describes the synthesis of enantiopure alcohols and diols by combining ruthenium-catalyzed redox reactions that lead to racemization or epimerization and lipase-catalyzed asymmetric trans-formations in one-pot.A mechanistic study of the unexpected facile formation of meso-diacetate products found in enzyme-catalyzed acetylations of alkanediols with Candida antarctica lipase B (CALB) was first performed. READ MORE
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12. Exploring Conjugate Addition Activity in Pseudozyma antarctica Lipase B
Abstract : Multifunctional enzymes have alternative functions or activities, known as “moonlighting” or “promiscuous”, which are often hidden behind a native enzyme activity and therefore only visible under special environmental conditions. In this thesis, the active-site of Pseudozyma (formerly Candida) antarctica lipase B was explored for a promiscuous conjugate addition activity. READ MORE
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13. Lipase catalysed reactions of terpenoids : formation of hemiacetal esters : resolution of cryptone and its transformation to cadinenes
Abstract : During attempted enzyme-catalysed resolution of sterically hindered secondary alcohols, hemiacetals and their esters were unexpectedly detected. Hemiacetal esters are reactive compounds that decompose to alcohol, aldehyde and acid under ordinary work-up conditions i.e. in contact with water, acid, or silica gel. READ MORE
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14. Hormone-Sensitive Lipase and Protein Kinase B; Molecular characterization in testis, adipose tissue and pancreatic beta cells
Abstract : Hormone-sensitive lipase (HSL) and protein kinase B (PKB) are enzymes that in different ways are associated with lipid metabolism. While HSL is the well-known lipolytic enzyme responsible for hydrolysis of stored triacylglycerols in adipose tissue, PKB is a recently identified serine/threonine protein kinase, ubiquitously expressed and involved in signal transduction pathways induced by insulin and growth factors. READ MORE
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15. Engineering of Candida antarctica Lipase A and B
Abstract : In organic chemistry, it is often desirable to have an efficient process yieldingpure product and not too much waste. When applicable, it is also desirable tohave a high enantioselective outcome. Enzymes are often displaying high regio-,chemo- and stereoselectivity. READ MORE