Search for dissertations about: "maleic"

Showing result 1 - 5 of 28 swedish dissertations containing the word maleic.

  1. 1. Covalent Surface Modification of Degradable Polymers for Increased Biocompatibility

    Author : Martina Källrot; Ann-Christine Albertsson; Mikael Lindström; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Vapor phase grafting; covalent surface modification; solvent free; nano patterned topography; degradable polymers; poly ε-caprolactone ; poly L-lactide ; poly lactide-co-glycolide ; poly trimethylene carbonate ; N-vinylpyrrolidone; maleic anhydride; acrylamide; Gasfasympning; kovalent ytmodifiering; lösningsmedelsfri; nedbrytbara polymerer; nanomönstrad topografi; poly L-laktid ; poly ε-kaprolakton ; poly laktid-co-glykolid ; poly trimetylen karbonat ; N-vinylpyrrolidon; maleinsyraanhydrid; akrylamid; Polymer chemistry; Polymerkemi;

    Abstract : Degradable polymers have gained an increased attention in the field of biomedical applications over the past decades, for example in tissue engineering. One way of improving the biocompatibility of these polymers is by chemical surface modification, however the risk of degradation during the modification procedure is a limiting factor. READ MORE

  2. 2. Steric Stabilization of Polylactide particles achieved by Covalent 'grafting-from' with Hydrophilic Polymers

    Author : Robertus Wahyu Nayan Nugroho; Ann-Christine Albertsson; Karin Odelius; Anders Höglund; Mark Rutland; Martina Janstål; KTH; []
    Keywords : Steric stabilization; AFM; hydrophilicity; surface modification; poly lactide ; acrylamide; acrylic acid; maleic anhydride;

    Abstract : Despite numerous advantages of using particles in a wide range of applications, they have one drawback that is their tendency to agglomerate. One way to overcome this problem is to sterically  stabilize the particles by introducing polymeric  chains covalently attached to the surface. READ MORE

  3. 3. Physical properties and crystallization of theophylline co-crystals

    Author : Shuo Zhang; Åke Rasmuson; Per Svensson; Mårten Behm; KTH; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; Theophylline; oxalic acid; glutaric acid; maleic acid; co-crystal; decomposition temperature; melting temperature; solubility; crystallization; Molecular transport processes in chemical process engineering; Molekylära transportprocesser i kemisk processteknik;

    Abstract : This work focuses on the physical properties and crystallization of theophyline co-crystals. Co-crystals of theophylline with oxalic acid, glutaric acid and maleic acid have been investigated. The DSC curves of these co-crystals show that their first endothermic peaks are all lower than the melting temperature of theophylline. READ MORE

  4. 4. Covalent Vapor-Phase Grafting of Degradable Polymers

    Author : Martina Källrot; Ann-Christine Albertsson; Maria Nowokowska; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Vapor-phase grafting; covalent surface modification; functionalization; solvent-free grafting; sub-micron patterned topography; scaffolds; degradable polymers; poly L-lactide ; poly ε-caprolactone ; poly trimethylene carbonate ; poly L-lactide-co-glycolide ; poly 1; 5-dioxepan-2-one-co-L-lactide ; poly ε-caprolactone-co-L-lactide ; N-vinylpyrrolidone; maleic anhydride; acrylamide; acrylic acid; hyaluronic acid; in vitro degradation; Gasfasympning; kovalent ytmodifiering; funktionalisering; lösningsmedelsfri ympning; sub-micrometer mönstrad topografi; nedbrytbara polymerer; poly L-laktid ; poly ε-kaprolakton ; poly trimetylen karbonat ; poly L-laktid-co-glykolid ; poly 1; 5-dioxepan-2-one-co-L-laktid ; poly ε-kaprolakton-co-L-laktid N-vinylpyrrolidon; maleinsyraanhydrid; akrylamid; akrylsyra; hyaluronsyra; in vitro nedbrytning; Polymer chemistry; Polymerkemi;

    Abstract : Gasfasympning är en del i den moderna strategin för optimering av den molekylära designen av biomaterial. Kovalent ytmodifiering med hydrofila vinylmonomerer och koppling med bioaktiva grupper används för att öka biokompatibiliteten och bioaktiviteten hos biomaterialen.. READ MORE

  5. 5. Structure-Reactivity Correlations for Reactions of Palladium(II) and Platinum(IV) Complexes

    Author : Tiesheng Shi; Kemiska institutionen; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; thiol; l-methionine; maleic acid; carboxylic acid; thioether; platinum IV ; palladium II ; linear free energy relationship; volumes of activation; structure-reactivity correlation; reduction; substitution; equilibria; kinetics; mechanism; glutathione; Animal physiology; Djurfysiologi;

    Abstract : The kinetics and mechanism for substitution reactions on tetraaquapalladium(II) by an extended series of thioethers, a great number of carboxylic acids, and olefins have been studied by use of UV-VIS, stopped-flow, and high-pressure stopped-flow spectrophotometry and NMR spectroscopy. Second-order rate constants k and activation parameters (activation enthalpies, entropies, and volumes) for formation of monodentate 1:1 complexes have been determined. READ MORE