Search for dissertations about: "mesityl"

Found 2 swedish dissertations containing the word mesityl.

  1. 1. Homoleptic Arylcopper Complexes

    Author : Henrik Eriksson; Chalmers tekniska högskola; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; cocrystallisation; Grignard; organocopper; bromide; thienyl; mesityl; crystal structure; synthesis; copper I ; arylcopper;

    Abstract : New arylcopper complexes have been synthesised and characterised structurally. The reaction between the Grignard reagent (viph)MgBr (viph = ortho-vinylphenyl) and CuCl has been studied and two unstable mixed aryl/halide intermediates, [Mg(THF)6][Cu5(viph)2Br4]2.THF and [Mg(THF)5Cl][Cu5(viph)4Br2]. READ MORE

  2. 2. Platinum(II) and Palladium (II) Complexes with Group 14 and 15 Donor Ligands. Synthesis, Structure and Substitution Mechanisms

    Author : Ola Wendt; Kemiska institutionen; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; mechanism; kinetics; substitution; platinum; palladium; aryl; silyl; nitrile; triphenylstibine; NMR; IR; Raman; X-ray crystallography; stopped-flow; synthesis; Inorganic chemistry; Oorganisk kemi;

    Abstract : The present thesis deals with Pd(II) and Pt(II) complexes with group 14 and 15 donor ligands. Such complexes have been prepared and investigated mainly with regard to their ground state structures and the mechanism according to which they undergo substitution. READ MORE