Search for dissertations about: "metal–metal bond"

Found 1 swedish dissertation containing the words metal–metal bond.

2. 1. Formation and Decomposition of Platinum–Thallium Bond, Kinetics and Mechanism. Structural Characterization of Some Metal Cyanides in the Solid State

   Author : Péter Nagy; KTH; []
   Keywords : NATURVETENSKAP; NATURAL SCIENCES; metal–metal bond; platinum; thallium; kinetics; mechanism; stopped flow; oxidative addition; cyano complexes; edta; redox reaction; metal cyanides; X–ray diffraction; Raman; NMR; mercury; palladium; nickel; one dimensional wire;

   Abstract : The kinetic and mechanistic features of a new series ofplatinum-thallium cyano compounds containing a direct andunsupported by ligands metal-metal bond have been studied insolution, using standard mix–and–measurespectrophotometric technique and stopped–flow method.These reactions are interpreted as oxidative addition of the cspecies to the square planar Pt(CN)42-complex. READ MORE