Search for dissertations about: "organic acids"

Showing result 16 - 20 of 363 swedish dissertations containing the words organic acids.

  2. 16. Synthesis of Organoboronic Acids and Applications in Asymmetric Organocatalysis

    Author : Sybrand Jonker; Kálmán Szabó; Jörg Pietruszka; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Boronic acid; BINOL; allylboration; propargylation; homologation; stereoselective synthesis; asymmetric synthesis; organocatalysis; allylboronic acid; allenylboronic acid; organisk kemi; Organic Chemistry;

    Abstract : Allyl- and allenylboronic acids are valuable reagents in organic synthesis due to their configurational stability and high reactivity. Few allyl- and allenylboronates are commercially available. Therefore, both the preparation and synthetic application of these organoboronic acids are subjects of study. READ MORE

  4. 17. Photoinitiated Radical Carbonylation Using [11C]Carbon Monoxide : 11C-Labelling of Aliphatic Carboxylic Acids, Esters, and Amides

    Author : Oleksiy Itsenko; Bengt Långström; Tor Kihlberg; Chryssostomos Chatgilialoglu; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Organic chemistry; 11C-labelling; radicals; carbonylation; carbon monoxide; solvent effects; sensitizers; sulfoxides; WAY-100635; PET; Organisk kemi; Organic chemistry; Organisk kemi;

    Abstract : One-step photoinitiated free radical carbonylation was employed for the rapid (5–7 min) labelling of aliphatic carboxylic acids, esters, and amides with a short-lived positron emitter 11C (t½ = 20.3 min) at the carbonyl position. The labelled compounds were synthesized from alkyl iodides (0.05–0. READ MORE

  5. 18. Production and transformation of organic compounds from renewable feedstock : Catalytic approaches

    Author : Elena Subbotina; Joseph Samec; Pieter Bruijnincx; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Lignin; biomass; lignin-first; catalytic fractionation; flow reactors; dibenzodioxocin; silanes; zeolites; visible light photocatalysis; dearomatization; spirolactones; organisk kemi; Organic Chemistry;

    Abstract : This thesis is focused on the development of strategies for lignocellulosic biomass valorization. The thesis consists of two parts.The first part of the presented work is related to the catalytic fractionation of biomass (lignin-first approach) and the production of monomeric compounds from lignocellulose. READ MORE

  6. 19. Carbocation Catalysis for Organic Synthesis

    Author : Shengjun Ni; Johan Franzén; Bernd Plietker; KTH; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; carbocation; trityl cation; Lewis acid catalyst; enantioselective; chiral counteranion; oxa-Diels–Alder; bromination; aldehyde–olefin metathesis; Kemi; Chemistry;

    Abstract : The most common view of carbocations in organic chemistry is that they are short-lived intermediates in several fundamental reactions, e.g. the classic SN1-reaction. READ MORE

  7. 20. Efficient and High-Yielding Routes to Diaryliodonium Salts

    Author : Marcin Bielawski; Berit Olofsson; Stockholms universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; Hypervalent Iodine Compounds; One-Pot Synthesis; Regiospecific Synthesis; Aromatic Substitution; Aryl Iodides; Arenes; Boronic Acids; Organic chemistry; Organisk kemi;

    Abstract : This thesis summarizes three novel and general reaction protocols for the synthesis of diaryliodonium salts. All protocols utilize mCPBA as oxidant and the acids used are either TfOH, to obtain triflate salts, or BF3•Et2O that gives the corresponding tetrafluoroborate salts in situ. READ MORE