Search for dissertations about: "potentiodynamic"

Showing result 1 - 5 of 9 swedish dissertations containing the word potentiodynamic.

  1. 1. Functional and Modular As=C and P=C Group Motifs

    Author : Daniel Morales Salazar; Andreas Orthaber; Jose Goicoechea; Uppsala universitet; []
    Keywords : NATURVETENSKAP; NATURAL SCIENCES; materials; physical chemistry; arsaalkenes; phosphaalkenes; DBU; fluorene; photochemistry; arsenic; phosphorus; carbon; hydrogen; sulfur; gold; copper; organic materials; organic electronics; molecular electronics; polymers; transition metal complexes; molecular materials; small molecule; hydrogen bonding; electrochemistry; cyclic voltammetry; chronoamperometry; electropolymerization; artificial intelligence; potentiodynamic; modularity; functionality; XPS; DFT; π-conjugation effects; 2D-NMR; disilenes; siliconoids; group motifs; functional group; emergence; reactivity; reactive systems; organometallic complexes; π-delocalization; low-coordinate; main group chemistry; heavy p-block elements; pnictogens; copper I complex; gold I complex; photosensitizer; XRD; spectroelectrochemistry; electrochromism; smart materials; synthesis; phosphaalkene ligands; imine ligands; hysteresis-like criteria; representative settings; optimal criteria; transient covalence; interactive image; conformer; isomer; ligand scrambling; nanomaterials; stimuli-responsive; optical properties; ligand design; molecular design; X-ray crystallography; emission; self-assembly; As=C; Si=Si; P=C; multiple bond; equilibrium; heteroalkenes; alkenes; reversibility; Raman; ATR-FTIR; ERDA; Kemi; Chemistry;

    Abstract : This work focuses on the design, synthesis, characterization, and application projections of low-coordinated heavy pnictogen-containing (described by the generic letter E, hence E=C) phosphaalkenes (P=C) and arsaalkenes (As=C), with emphasis on the E=C group motifs. The work aims to understand their functional and modular character, reactivity, and potential applications by stabilizing, isolating, and characterizing these species in low-coordination environments. READ MORE

  2. 2. Studies of surface treatments of stainless steel for improved corrosion resistance

    Author : Daniel Wallinder; KTH; []
    Keywords : stainless steel; iron; chromium; passivity; passive film; pickling; polishing; passivation; bright-annealing; XPS; SIMS; EIS; potentiostatic polarization; potentiodynamic polarization; aqueous corrosion; localized corrosion; atmospheric corrosion; hi;

    Abstract : .... READ MORE

  3. 3. Fabrication and Corrosion Properties of Nickel Silicides Thin Films

    Author : Eric Tam; Chalmers tekniska högskola; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; nickel silicides; ion-beam sputter deposition; potentiodynamic polarisation measurements; X-ray photoelectron spectroscopy; corrosion.; thin films;

    Abstract : Surface engineering is a vital issue in engineering materials design. The enhancement of surface properties extends the materials lifetime and improves the materials performance without changing the bulk properties. Thin film deposition is one of the most commonly applied techniques in this field. READ MORE

  4. 4. Tailoring of Transition Metal Silicides as Protective Thin Films on Austenitic Stainless Steel

    Author : Eric Tam; Chalmers tekniska högskola; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; NATURVETENSKAP; NATURAL SCIENCES; Rockwell-C adhesion test; X-ray diffractrometry XRD ; Pretorius’ effective heat of formation EHF model; Ion-beam sputter deposition IBSD ; Reciprocating sliding wear test; Corrosion; Stainless steels; Thin films; Tribology; Transition metal silicides; X-ray photoelectron spectroscopy XPS ; Potentiodynamic polarisation measurements;

    Abstract : The objective of this study is to make use of transition metal silicides in a novel way as protective thin films on engineering metals. It can then be possible to take advantage of the potentially good corrosion resistance of metal silicides while compensating for their brittle nature by the ductile bulk material. READ MORE

  5. 5. Nanocomposite films for corrosion protection

    Author : Majid Sababi; Jinshan Pan; J.M.C. (Arjan) Mol; KTH; []
    Keywords : TEKNIK OCH TEKNOLOGIER; ENGINEERING AND TECHNOLOGY; corrosion protection; nanocomposite; coating; tool alloy; layer‐by‐layer; polarization; passivity; nanomechanical; topography; Mefp‐ 1; ceria nanoparticle; PAni; UV‐cure; AFM; Peak Force QNM; EIS; SEM; CRM; QCM‐D; ATR‐FTIR;

    Abstract : This thesis describes technical and scientific aspects of new types of composite films/coatings for corrosion protection of carbon steel, composite films with nanometer thickness consisting of mussel adhesive protein (Mefp‐1) and ceria nanoparticles, and polymeric composite coatings with micrometre thickness consisting of conducting polymer and ceria nanoparticles in a UV‐curing polyester acrylate (PEA) resin.The influence of microstructure on corrosion behaviour was studied for a Fe‐Cr‐V‐N alloy containing micro‐sized nitrides with different chemical composition spread in martensitic alloy matrix. READ MORE